Abstract
The previously unobserved O-2(b(1)Sigma(g)(+)) + O(P-3(J)) spin-forbidden photodissociation channel of ozone is identified following absorption in the Huggins band (335-352 nm). The nascent O-2(b (1)Sigma(g)(+)) photofragments rue detected by two-colour resonance enhanced multiphoton ionisation (REMPI) via the d3s sigma(g) (1)Pi(g) Rydberg state. (C) 1998 Elsevier Science B.V. All rights reserved.
| Original language | English |
|---|---|
| Pages (from-to) | 368-374 |
| Number of pages | 7 |
| Journal | Chemical Physics Letters |
| Volume | 298 |
| Issue number | 4-6 |
| Publication status | Published - 18 Dec 1998 |
Keywords / Materials (for Non-textual outputs)
- RYDBERG-VALENCE INTERACTIONS
- RELATIVE QUANTUM YIELDS
- MULTIPHOTON IONIZATION
- EXCITED-STATES
- SPECTROSCOPY
- PHOTOLYSIS
- O-2
- PREDISSOCIATION
- O(D-1)
- BAND