Photoreactive furan derivatives

E Lasseuguette; A Gandini; HJ Timpe

doi:10.1016/j.photochem.2005.03.012

Photoreactive furan derivatives

E Lasseuguette^*, A Gandini, HJ Timpe

^*Corresponding author for this work

School of Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Several furan compounds bearing conjugated trans C=C plus carbonyl moieties appended at the C2 position of the heterocycle were synthesized and characterized. Near-UV irradiation in bulk and in concentrated solutions induced their dimerization through a [pi 2 + pi 2] cycloaddition reaction between an excited and a ground state molecule. In dilute solutions, the excited species underwent predominantly trans-cis isomerization to give the equilibrium mixture of the isomers. (c) 2005 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	222-228
Number of pages	7
Journal	Journal of Photochemistry and Photobiology A: Chemistry
Volume	174
Issue number	3
DOIs	https://doi.org/10.1016/j.photochem.2005.03.012
Publication status	Published - 1 Sept 2005

Keywords / Materials (for Non-textual outputs)

furan
photochemistry
dimerization
isomerization
cycloaddition
kinetic
PHOTODIMERIZATION
POLYMERS
ACID
ESTERS

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10.1016/j.photochem.2005.03.012

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title = "Photoreactive furan derivatives",

abstract = "Several furan compounds bearing conjugated trans C=C plus carbonyl moieties appended at the C2 position of the heterocycle were synthesized and characterized. Near-UV irradiation in bulk and in concentrated solutions induced their dimerization through a [pi 2 + pi 2] cycloaddition reaction between an excited and a ground state molecule. In dilute solutions, the excited species underwent predominantly trans-cis isomerization to give the equilibrium mixture of the isomers. (c) 2005 Elsevier B.V. All rights reserved.",

keywords = "furan, photochemistry, dimerization, isomerization, cycloaddition, kinetic, PHOTODIMERIZATION, POLYMERS, ACID, ESTERS",

author = "E Lasseuguette and A Gandini and HJ Timpe",

year = "2005",

month = sep,

day = "1",

doi = "10.1016/j.photochem.2005.03.012",

language = "English",

volume = "174",

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journal = "Journal of Photochemistry and Photobiology A: Chemistry",

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TY - JOUR

T1 - Photoreactive furan derivatives

AU - Lasseuguette, E

AU - Gandini, A

AU - Timpe, HJ

PY - 2005/9/1

Y1 - 2005/9/1

N2 - Several furan compounds bearing conjugated trans C=C plus carbonyl moieties appended at the C2 position of the heterocycle were synthesized and characterized. Near-UV irradiation in bulk and in concentrated solutions induced their dimerization through a [pi 2 + pi 2] cycloaddition reaction between an excited and a ground state molecule. In dilute solutions, the excited species underwent predominantly trans-cis isomerization to give the equilibrium mixture of the isomers. (c) 2005 Elsevier B.V. All rights reserved.

AB - Several furan compounds bearing conjugated trans C=C plus carbonyl moieties appended at the C2 position of the heterocycle were synthesized and characterized. Near-UV irradiation in bulk and in concentrated solutions induced their dimerization through a [pi 2 + pi 2] cycloaddition reaction between an excited and a ground state molecule. In dilute solutions, the excited species underwent predominantly trans-cis isomerization to give the equilibrium mixture of the isomers. (c) 2005 Elsevier B.V. All rights reserved.

KW - furan

KW - photochemistry

KW - dimerization

KW - isomerization

KW - cycloaddition

KW - kinetic

KW - PHOTODIMERIZATION

KW - POLYMERS

KW - ACID

KW - ESTERS

U2 - 10.1016/j.photochem.2005.03.012

DO - 10.1016/j.photochem.2005.03.012

M3 - Article

SN - 1010-6030

VL - 174

SP - 222

EP - 228

JO - Journal of Photochemistry and Photobiology A: Chemistry

JF - Journal of Photochemistry and Photobiology A: Chemistry

IS - 3

ER -

Photoreactive furan derivatives

Abstract

Keywords / Materials (for Non-textual outputs)

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