Polymers of intrinsic microporosity as high temperature templates for the formation of nanofibrous oxides

H. Al Kutubi; L. Rassaei; W. Olthuis; G. W. Nelson; J. S. Foord; P. Holdway; Mariolino Carta; R. Malpass-Evans; N. B. McKeown; S. C. Tsang; R. Castaing; T. R. Forder; M. D. Jones; D. He; F. Marken

doi:10.1039/c5ra15131g

Polymers of intrinsic microporosity as high temperature templates for the formation of nanofibrous oxides

H. Al Kutubi, L. Rassaei, W. Olthuis, G. W. Nelson, J. S. Foord, P. Holdway, Mariolino Carta, R. Malpass-Evans, N. B. McKeown, S. C. Tsang, R. Castaing, T. R. Forder, M. D. Jones, D. He, F. Marken^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The highly rigid molecular structure of Polymers of Intrinsic Microporosity (PIM) - associated with a high thermolysis threshold - combined with the possibility to fill intrinsic micropores allows the direct "one-step" templated conversion of metal nitrates into nanostructured metal oxides. This is demonstrated here with PIM-EA-TB and with PIM-1 for the conversion of Pr(NO3)(3) to Pr6O11.

Original language	English
Pages (from-to)	73323-73326
Number of pages	4
Journal	RSC Advances
Volume	5
Issue number	89
DOIs	https://doi.org/10.1039/c5ra15131g
Publication status	Published - 2015

Keywords

DOPED INDIUM OXIDE
PRASEODYMIUM OXIDE
DEPOSITION
SEPARATIONS
STORAGE
SOLIDS
FILMS
PIMS

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C5RA15131GFinal published version, 2.27 MB

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Al Kutubi, H., Rassaei, L., Olthuis, W., Nelson, G. W., Foord, J. S., Holdway, P., Carta, M., Malpass-Evans, R., McKeown, N. B., Tsang, S. C., Castaing, R., Forder, T. R., Jones, M. D., He, D., & Marken, F. (2015). Polymers of intrinsic microporosity as high temperature templates for the formation of nanofibrous oxides. RSC Advances, 5(89), 73323-73326. https://doi.org/10.1039/c5ra15131g

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title = "Polymers of intrinsic microporosity as high temperature templates for the formation of nanofibrous oxides",

abstract = "The highly rigid molecular structure of Polymers of Intrinsic Microporosity (PIM) - associated with a high thermolysis threshold - combined with the possibility to fill intrinsic micropores allows the direct {"}one-step{"} templated conversion of metal nitrates into nanostructured metal oxides. This is demonstrated here with PIM-EA-TB and with PIM-1 for the conversion of Pr(NO3)(3) to Pr6O11.",

keywords = "DOPED INDIUM OXIDE, PRASEODYMIUM OXIDE, DEPOSITION, SEPARATIONS, STORAGE, SOLIDS, FILMS, PIMS",

author = "{Al Kutubi}, H. and L. Rassaei and W. Olthuis and Nelson, {G. W.} and Foord, {J. S.} and P. Holdway and Mariolino Carta and R. Malpass-Evans and McKeown, {N. B.} and Tsang, {S. C.} and R. Castaing and Forder, {T. R.} and Jones, {M. D.} and D. He and F. Marken",

year = "2015",

doi = "10.1039/c5ra15131g",

language = "English",

volume = "5",

pages = "73323--73326",

journal = "RSC Advances",

issn = "2046-2069",

publisher = "Royal Society of Chemistry",

number = "89",

}

Al Kutubi, H, Rassaei, L, Olthuis, W, Nelson, GW, Foord, JS, Holdway, P, Carta, M, Malpass-Evans, R, McKeown, NB, Tsang, SC, Castaing, R, Forder, TR, Jones, MD, He, D & Marken, F 2015, 'Polymers of intrinsic microporosity as high temperature templates for the formation of nanofibrous oxides', RSC Advances, vol. 5, no. 89, pp. 73323-73326. https://doi.org/10.1039/c5ra15131g

TY - JOUR

T1 - Polymers of intrinsic microporosity as high temperature templates for the formation of nanofibrous oxides

AU - Al Kutubi, H.

AU - Rassaei, L.

AU - Olthuis, W.

AU - Nelson, G. W.

AU - Foord, J. S.

AU - Holdway, P.

AU - Carta, Mariolino

AU - Malpass-Evans, R.

AU - McKeown, N. B.

AU - Tsang, S. C.

AU - Castaing, R.

AU - Forder, T. R.

AU - Jones, M. D.

AU - He, D.

AU - Marken, F.

PY - 2015

Y1 - 2015

N2 - The highly rigid molecular structure of Polymers of Intrinsic Microporosity (PIM) - associated with a high thermolysis threshold - combined with the possibility to fill intrinsic micropores allows the direct "one-step" templated conversion of metal nitrates into nanostructured metal oxides. This is demonstrated here with PIM-EA-TB and with PIM-1 for the conversion of Pr(NO3)(3) to Pr6O11.

AB - The highly rigid molecular structure of Polymers of Intrinsic Microporosity (PIM) - associated with a high thermolysis threshold - combined with the possibility to fill intrinsic micropores allows the direct "one-step" templated conversion of metal nitrates into nanostructured metal oxides. This is demonstrated here with PIM-EA-TB and with PIM-1 for the conversion of Pr(NO3)(3) to Pr6O11.

KW - DOPED INDIUM OXIDE

KW - PRASEODYMIUM OXIDE

KW - DEPOSITION

KW - SEPARATIONS

KW - STORAGE

KW - SOLIDS

KW - FILMS

KW - PIMS

U2 - 10.1039/c5ra15131g

DO - 10.1039/c5ra15131g

M3 - Article

VL - 5

SP - 73323

EP - 73326

JO - RSC Advances

JF - RSC Advances

SN - 2046-2069

IS - 89

ER -

Polymers of intrinsic microporosity as high temperature templates for the formation of nanofibrous oxides

Abstract

Keywords

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