Postsynthetic bromination of UiO-66 analogues: altering linker flexibility and mechanical compliance

Ross J Marshall; Tom Richards; Claire L Hobday; Colin F Murphie; Claire Wilson; Stephen A Moggach; Thomas D Bennett; Ross S Forgan

doi:10.1039/c5dt03178h

Postsynthetic bromination of UiO-66 analogues: altering linker flexibility and mechanical compliance

Ross J Marshall, Tom Richards, Claire L Hobday, Colin F Murphie, Claire Wilson, Stephen A Moggach, Thomas D Bennett, Ross S Forgan

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Abstract / Description of output

A new member of the UiO-66 series of zirconium metal-organic frameworks (MOFs) is reported, and the postsynthetic bromination of its integral alkene moeities in a single-crystal to single-crystal manner is fully characterised. Nanoindentation is used to probe the bromination of unsaturated carbon-carbon bonds, in it and an analogous Zr MOF, which leads to more compliant materials with lower elastic moduli.

Original language	English
Pages (from-to)	4132-4135
Number of pages	4
Journal	Dalton Transactions
Volume	45
Issue number	10
Early online date	11 Nov 2015
DOIs	https://doi.org/10.1039/c5dt03178h
Publication status	Published - 1 Mar 2016

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title = "Postsynthetic bromination of UiO-66 analogues: altering linker flexibility and mechanical compliance",

abstract = "A new member of the UiO-66 series of zirconium metal-organic frameworks (MOFs) is reported, and the postsynthetic bromination of its integral alkene moeities in a single-crystal to single-crystal manner is fully characterised. Nanoindentation is used to probe the bromination of unsaturated carbon-carbon bonds, in it and an analogous Zr MOF, which leads to more compliant materials with lower elastic moduli.",

author = "Marshall, {Ross J} and Tom Richards and Hobday, {Claire L} and Murphie, {Colin F} and Claire Wilson and Moggach, {Stephen A} and Bennett, {Thomas D} and Forgan, {Ross S}",

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T2 - altering linker flexibility and mechanical compliance

AU - Marshall, Ross J

AU - Richards, Tom

AU - Hobday, Claire L

AU - Murphie, Colin F

AU - Wilson, Claire

AU - Moggach, Stephen A

AU - Bennett, Thomas D

AU - Forgan, Ross S

PY - 2016/3/1

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N2 - A new member of the UiO-66 series of zirconium metal-organic frameworks (MOFs) is reported, and the postsynthetic bromination of its integral alkene moeities in a single-crystal to single-crystal manner is fully characterised. Nanoindentation is used to probe the bromination of unsaturated carbon-carbon bonds, in it and an analogous Zr MOF, which leads to more compliant materials with lower elastic moduli.

AB - A new member of the UiO-66 series of zirconium metal-organic frameworks (MOFs) is reported, and the postsynthetic bromination of its integral alkene moeities in a single-crystal to single-crystal manner is fully characterised. Nanoindentation is used to probe the bromination of unsaturated carbon-carbon bonds, in it and an analogous Zr MOF, which leads to more compliant materials with lower elastic moduli.

U2 - 10.1039/c5dt03178h

DO - 10.1039/c5dt03178h

M3 - Article

C2 - 26583777

SN - 0300-9246

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SP - 4132

EP - 4135

JO - Dalton Transactions

JF - Dalton Transactions

IS - 10

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Postsynthetic bromination of UiO-66 analogues: altering linker flexibility and mechanical compliance

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