Potassium bis(4,5-dimercapto-1,3-dithiole-2-thionato)nickelate 1,4,7,10,13,16-hexaoxa-2,3 : 11,12-dibenzocyclooctadeca-2,11-diene propanone solvate

K Shitagami, T Akutagawa, T Hasegawa, T Nakamura, N Robertson

Research output: Contribution to journalArticlepeer-review

Abstract

In the title compound, K[Ni(C3S5)(2)]C20H24O6 .C3H6O, K+ is incorporated in the cavity of the 1,4,7,10,13,16-hexaoxa-2,3:11,12-dibenzocyclooctadeca-2,11-diene (DB18c6) molecule and is coordinated by the six DB18c6 O atoms and the propanone O atom. Two {K+ (DB18c6)[(CH3)(2) CO]} units form a dimer which is aligned in a one-dimensional manner along the a axis through a face-to-face interaction between the benzene rings of neighboring DB18c6 molecules. [Ni(dmit)(2)](-) anions are also aligned along the a axis through side-by-side S . . .S interactions.

Original languageEnglish
Pages (from-to)1271-1273
Number of pages3
JournalActa Crystallographica Section C - Crystal Structure Communications
Volume57
DOIs
Publication statusPublished - Nov 2001

Keywords

  • CROWN-ETHERS
  • CATIONS
  • SALTS
  • CHAIN

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