Pressure-Driven Orbital Reorientations and Coordination-Sphere Reconstructions in [CuF2(H2O)2(pyz)]

Alessandro Prescimone; Chelsey Morien; David Allan; John A. Schlueter; Stan W. Tozer; Jamie L. Manson; Simon Parsons; Euan K. Brechin; Stephen Hill

doi:10.1002/anie.201202367

Pressure-Driven Orbital Reorientations and Coordination-Sphere Reconstructions in [CuF2(H2O)2(pyz)]

Alessandro Prescimone, Chelsey Morien, David Allan, John A. Schlueter, Stan W. Tozer, Jamie L. Manson, Simon Parsons, Euan K. Brechin, Stephen Hill

Research output: Contribution to journal › Meeting abstract › peer-review

Abstract / Description of output

Successive reorientations of the Jahn–Teller axes associated with the CuII ions accompany a series of pronounced structural transitions in the title compound, as is shown by X-ray crystallography and high-frequency EPR measurements. The second transition forces a dimerization involving two thirds of the CuII sites due to ejection of one of the water molecules from the coordination sphere.

Original language	English
Pages (from-to)	7490–7494
Number of pages	5
Journal	Angewandte Chemie International Edition
Volume	51
Issue number	30
DOIs	https://doi.org/10.1002/anie.201202367
Publication status	Published - 2012
Event	245th National Spring Meeting of the American-Chemical-Society (ACS) - New Orleans, New Orleans, Lao People's Democratic Republic Duration: 7 Apr 2013 → 11 Apr 2013

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10.1002/anie.201202367

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http://onlinelibrary.wiley.com/doi/10.1002/anie.201202367/full

EPR characterization of molecular magneto-structural correlations under pressure
Brechin, E., Kamenev, K. & Parsons, S.
EPSRC
1/10/09 → 31/12/12
Project: Research

Cite this

@article{a0584c0c229249059e83f258c8a5e96d,

title = "Pressure-Driven Orbital Reorientations and Coordination-Sphere Reconstructions in [CuF2(H2O)2(pyz)]",

abstract = "Successive reorientations of the Jahn–Teller axes associated with the CuII ions accompany a series of pronounced structural transitions in the title compound, as is shown by X-ray crystallography and high-frequency EPR measurements. The second transition forces a dimerization involving two thirds of the CuII sites due to ejection of one of the water molecules from the coordination sphere.",

author = "Alessandro Prescimone and Chelsey Morien and David Allan and Schlueter, {John A.} and Tozer, {Stan W.} and Manson, {Jamie L.} and Simon Parsons and Brechin, {Euan K.} and Stephen Hill",

year = "2012",

doi = "10.1002/anie.201202367",

language = "English",

volume = "51",

pages = "7490–7494",

journal = "Angewandte Chemie International Edition",

issn = "1433-7851",

publisher = "Wiley-VCH",

number = "30",

note = "245th National Spring Meeting of the American-Chemical-Society (ACS) ; Conference date: 07-04-2013 Through 11-04-2013",

}

TY - JOUR

T1 - Pressure-Driven Orbital Reorientations and Coordination-Sphere Reconstructions in [CuF2(H2O)2(pyz)]

AU - Prescimone, Alessandro

AU - Morien, Chelsey

AU - Allan, David

AU - Schlueter, John A.

AU - Tozer, Stan W.

AU - Manson, Jamie L.

AU - Parsons, Simon

AU - Brechin, Euan K.

AU - Hill, Stephen

PY - 2012

Y1 - 2012

N2 - Successive reorientations of the Jahn–Teller axes associated with the CuII ions accompany a series of pronounced structural transitions in the title compound, as is shown by X-ray crystallography and high-frequency EPR measurements. The second transition forces a dimerization involving two thirds of the CuII sites due to ejection of one of the water molecules from the coordination sphere.

AB - Successive reorientations of the Jahn–Teller axes associated with the CuII ions accompany a series of pronounced structural transitions in the title compound, as is shown by X-ray crystallography and high-frequency EPR measurements. The second transition forces a dimerization involving two thirds of the CuII sites due to ejection of one of the water molecules from the coordination sphere.

U2 - 10.1002/anie.201202367

DO - 10.1002/anie.201202367

M3 - Meeting abstract

SN - 1433-7851

VL - 51

SP - 7490

EP - 7494

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 30

T2 - 245th National Spring Meeting of the American-Chemical-Society (ACS)

Y2 - 7 April 2013 through 11 April 2013

ER -

Pressure-Driven Orbital Reorientations and Coordination-Sphere Reconstructions in [CuF2(H2O)2(pyz)]

Abstract / Description of output

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EPR characterization of molecular magneto-structural correlations under pressure

Cite this