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Successive reorientations of the Jahn–Teller axes associated with the CuII ions accompany a series of pronounced structural transitions in the title compound, as is shown by X-ray crystallography and high-frequency EPR measurements. The second transition forces a dimerization involving two thirds of the CuII sites due to ejection of one of the water molecules from the coordination sphere.
|Number of pages||5|
|Journal||Angewandte Chemie International Edition|
|Publication status||Published - 2012|
|Event||245th National Spring Meeting of the American-Chemical-Society (ACS) - New Orleans, New Orleans, Lao People's Democratic Republic|
Duration: 7 Apr 2013 → 11 Apr 2013
FingerprintDive into the research topics of 'Pressure-Driven Orbital Reorientations and Coordination-Sphere Reconstructions in [CuF2(H2O)2(pyz)]'. Together they form a unique fingerprint.
- 1 Finished
EPR characterization of molecular magneto-structural correlations under pressure
Brechin, E., Kamenev, K. & Parsons, S.
1/10/09 → 31/12/12