Pseudo-potentiostatic electrolysis by potential buffering induced by the oxygen evolution reaction

S. Fierro; E. Passas-Lagos; C. Comninellis; E. Chatzisymeon; D. Mantzavinos

doi:10.1016/j.elecom.2009.04.038

Pseudo-potentiostatic electrolysis by potential buffering induced by the oxygen evolution reaction

S. Fierro, E. Passas-Lagos, C. Comninellis, E. Chatzisymeon, D. Mantzavinos

School of Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

A new approach is proposed in order to perform electrochemical oxidation of organics by working under galvanostatic conditions with the potential 'buffered' by the competing side reaction of oxygen evolution (OER). According to this process the working potential is fixed by the nature of electrode material and is buffered during organics oxidation by the side reaction of OER. This principle has been used for the selective oxidation of some model organic compounds on Ti/IrO anode.

Original language	English
Pages (from-to)	1358-1361
Number of pages	4
Journal	Electrochemistry communications
Volume	11
Issue number	7
DOIs	https://doi.org/10.1016/j.elecom.2009.04.038
Publication status	Published - 1 Jul 2009

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10.1016/j.elecom.2009.04.038

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abstract = "A new approach is proposed in order to perform electrochemical oxidation of organics by working under galvanostatic conditions with the potential 'buffered' by the competing side reaction of oxygen evolution (OER). According to this process the working potential is fixed by the nature of electrode material and is buffered during organics oxidation by the side reaction of OER. This principle has been used for the selective oxidation of some model organic compounds on Ti/IrO anode.",

author = "S. Fierro and E. Passas-Lagos and C. Comninellis and E. Chatzisymeon and D. Mantzavinos",

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AU - Chatzisymeon, E.

AU - Mantzavinos, D.

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N2 - A new approach is proposed in order to perform electrochemical oxidation of organics by working under galvanostatic conditions with the potential 'buffered' by the competing side reaction of oxygen evolution (OER). According to this process the working potential is fixed by the nature of electrode material and is buffered during organics oxidation by the side reaction of OER. This principle has been used for the selective oxidation of some model organic compounds on Ti/IrO anode.

AB - A new approach is proposed in order to perform electrochemical oxidation of organics by working under galvanostatic conditions with the potential 'buffered' by the competing side reaction of oxygen evolution (OER). According to this process the working potential is fixed by the nature of electrode material and is buffered during organics oxidation by the side reaction of OER. This principle has been used for the selective oxidation of some model organic compounds on Ti/IrO anode.

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Pseudo-potentiostatic electrolysis by potential buffering induced by the oxygen evolution reaction

Abstract

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