TY - JOUR
T1 - Pseudo-potentiostatic electrolysis by potential buffering induced by the oxygen evolution reaction
AU - Fierro, S.
AU - Passas-Lagos, E.
AU - Comninellis, C.
AU - Chatzisymeon, E.
AU - Mantzavinos, D.
PY - 2009/7/1
Y1 - 2009/7/1
N2 - A new approach is proposed in order to perform electrochemical oxidation of organics by working under galvanostatic conditions with the potential 'buffered' by the competing side reaction of oxygen evolution (OER). According to this process the working potential is fixed by the nature of electrode material and is buffered during organics oxidation by the side reaction of OER. This principle has been used for the selective oxidation of some model organic compounds on Ti/IrO anode.
AB - A new approach is proposed in order to perform electrochemical oxidation of organics by working under galvanostatic conditions with the potential 'buffered' by the competing side reaction of oxygen evolution (OER). According to this process the working potential is fixed by the nature of electrode material and is buffered during organics oxidation by the side reaction of OER. This principle has been used for the selective oxidation of some model organic compounds on Ti/IrO anode.
UR - http://www.scopus.com/inward/record.url?eid=2-s2.0-67649491079&partnerID=8YFLogxK
U2 - 10.1016/j.elecom.2009.04.038
DO - 10.1016/j.elecom.2009.04.038
M3 - Article
AN - SCOPUS:67649491079
SN - 1388-2481
VL - 11
SP - 1358
EP - 1361
JO - Electrochemistry communications
JF - Electrochemistry communications
IS - 7
ER -