Rate enhancement by ethylene in the Ru-catalyzed ring-closing metathesis of enynes: Evidence for an "ene-then-yne" pathway that diverts through a second catalytic cycle

GC Lloyd-Jones; RG Margue; JG de Vries

doi:10.1002/anie.200502243

Rate enhancement by ethylene in the Ru-catalyzed ring-closing metathesis of enynes: Evidence for an "ene-then-yne" pathway that diverts through a second catalytic cycle

GC Lloyd-Jones^*, RG Margue, JG de Vries

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Original language	English
Pages (from-to)	7442-7447
Number of pages	6
Journal	Angewandte Chemie International Edition
Volume	44
Issue number	45
DOIs	https://doi.org/10.1002/anie.200502243
Publication status	Published - 2005

Keywords

carbenes
isotopic labeling
metathesis
reaction mechanisms
ruthenium
OLEFIN METATHESIS
CARBENE COMPLEXES
RUTHENIUM
MECHANISM
LIGANDS
ALKYNES
DIENES

Access to Document

10.1002/anie.200502243

Cite this

@article{a8f40ccc80014705aa5b6c27322a508c,

title = "Rate enhancement by ethylene in the Ru-catalyzed ring-closing metathesis of enynes: Evidence for an {"}ene-then-yne{"} pathway that diverts through a second catalytic cycle",

keywords = "carbenes, isotopic labeling, metathesis, reaction mechanisms, ruthenium, OLEFIN METATHESIS, CARBENE COMPLEXES, RUTHENIUM, MECHANISM, LIGANDS, ALKYNES, DIENES",

author = "GC Lloyd-Jones and RG Margue and {de Vries}, JG",

year = "2005",

doi = "10.1002/anie.200502243",

language = "English",

volume = "44",

pages = "7442--7447",

journal = "Angewandte Chemie International Edition",

issn = "1433-7851",

publisher = "WILEY-V C H VERLAG GMBH",

number = "45",

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TY - JOUR

T1 - Rate enhancement by ethylene in the Ru-catalyzed ring-closing metathesis of enynes

T2 - Evidence for an "ene-then-yne" pathway that diverts through a second catalytic cycle

AU - Lloyd-Jones, GC

AU - Margue, RG

AU - de Vries, JG

PY - 2005

Y1 - 2005

KW - carbenes

KW - isotopic labeling

KW - metathesis

KW - reaction mechanisms

KW - ruthenium

KW - OLEFIN METATHESIS

KW - CARBENE COMPLEXES

KW - RUTHENIUM

KW - MECHANISM

KW - LIGANDS

KW - ALKYNES

KW - DIENES

U2 - 10.1002/anie.200502243

DO - 10.1002/anie.200502243

M3 - Article

VL - 44

SP - 7442

EP - 7447

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

SN - 1433-7851

IS - 45

ER -