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Abstract / Description of output
The synthesis and full characterization of the redox-active nickel triad mixed-ligand dithiolene complexes based on Bz(2)pipdt = 1,4-dibenzylpiperazine-3,2-dithione and dmit = 2-thioxo-1,3-dithiole-4,5-dithiolate ligands are reported. These complexes show a reversibly bleacheable solvatochromic peak and a remarkably high negative molecular first hyperpolarizability, whose values depend on the metal being highest for the platinum(II) compound.
Original language | English |
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Pages (from-to) | 2058-2060 |
Number of pages | 3 |
Journal | Inorganic Chemistry |
Volume | 50 |
Issue number | 6 |
DOIs | |
Publication status | Published - 21 Mar 2011 |
Keywords / Materials (for Non-textual outputs)
- M(DIIMINE)(DITHIOLATE) COMPLEXES
- CRYSTAL-STRUCTURE
- DFT
- HYPERPOLARIZABILITIES
- TDDFT
- DYES
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