Regioselective electrophilic borylation of haloarenes

Alessandro Del Grosso; Josue Ayuso Carrillo; Michael J. Ingleson

doi:10.1039/c4cc10153g

Regioselective electrophilic borylation of haloarenes

Alessandro Del Grosso, Josue Ayuso Carrillo, Michael J. Ingleson^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Haloarenes undergo direct borylation using amine:BCl₃:AlCl₃ in the ratio of 1:1:2. After esterification the pinacol boronate esters are isolated in good yield with regioselectivity controlled by steric and electronic effects.

Original language	English
Pages (from-to)	2878-2881
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	14
DOIs	https://doi.org/10.1039/c4cc10153g
Publication status	Published - 18 Feb 2015

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@article{076f430d01924b39ae43009ca0e3f8ab,

title = "Regioselective electrophilic borylation of haloarenes",

abstract = "Haloarenes undergo direct borylation using amine:BCl3:AlCl3 in the ratio of 1:1:2. After esterification the pinacol boronate esters are isolated in good yield with regioselectivity controlled by steric and electronic effects.",

author = "{Del Grosso}, Alessandro and {Ayuso Carrillo}, Josue and Ingleson, {Michael J.}",

year = "2015",

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doi = "10.1039/c4cc10153g",

language = "English",

volume = "51",

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journal = "Chemical Communications",

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T1 - Regioselective electrophilic borylation of haloarenes

AU - Del Grosso, Alessandro

AU - Ayuso Carrillo, Josue

AU - Ingleson, Michael J.

PY - 2015/2/18

Y1 - 2015/2/18

N2 - Haloarenes undergo direct borylation using amine:BCl3:AlCl3 in the ratio of 1:1:2. After esterification the pinacol boronate esters are isolated in good yield with regioselectivity controlled by steric and electronic effects.

AB - Haloarenes undergo direct borylation using amine:BCl3:AlCl3 in the ratio of 1:1:2. After esterification the pinacol boronate esters are isolated in good yield with regioselectivity controlled by steric and electronic effects.

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U2 - 10.1039/c4cc10153g

DO - 10.1039/c4cc10153g

M3 - Article

C2 - 25582820

AN - SCOPUS:84922572671

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SP - 2878

EP - 2881

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 14

ER -

Regioselective electrophilic borylation of haloarenes

Abstract

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