Abstract / Description of output
Vacuum-ultraviolet fluorescence excitation and resonance enhanced multiphoton ionization (REMPI) spectra of IBr, cooled in a free-jet expansion, are reported. Resonance structure, observed in the region lambda > 179 nm, is greatly reduced on cooling and is ascribed to heterogeneous coupling between the E(0+) ion-pair state and the a6 Rydberg state. Observation of a new Rydberg series b6'[2PI1/2]c6s(0+)
Original language | English |
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Pages (from-to) | 4582-4588 |
Number of pages | 7 |
Journal | The Journal of physical chemistry |
Volume | 97 |
Issue number | 18 |
Publication status | Published - 6 May 1993 |
Keywords / Materials (for Non-textual outputs)
- ION-PAIR STATE
- LASER
- ABSORPTION
- I2