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Abstract / Description of output
Dialumenes are neutral Al(I) compounds with Al=Al multiple bonds. We report the isolation of an amidophosphine-supported dialumene. Our X-ray crystallographic, spectroscopic, and DFT computational analyses reveal a long and extreme trans-bent Al=Al bond with low dissociation energy and bond-order. In solution, the dialumene can dissociate into monomeric Al(I) species. Reactivity studies reveal two modes of reaction: as dialumene or as aluminyl monomers.
Original language | English |
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Journal | Angewandte Chemie International Edition |
Early online date | 14 Sept 2021 |
DOIs | |
Publication status | E-pub ahead of print - 14 Sept 2021 |
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