Rheological design of thickened alcohol-based hand rubs

Andreia F Silva*, Tiffany A Wood, Daniel J M Hodgson, John R Royer, Job H J Thijssen, Alex Lips, Wilson C K Poon*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

The handleability and sensory perception of hand sanitisers by consumers affect the hygiene outcome. Spillage may result in under-dosing and poor sensory properties can lead to under-utilisation. We first propose four principles (low runoff, spreadability, smoothness and non-stickiness) for designing the rheology of thickened alcohol-based hand rubs with acceptable handleability and hand feel. We then evaluate a commercial hand gel and a variety of simplified formulations thickened with microgels (Carbopol 974P, Carbopol Ultrez 20 and Sepimax Zen), or linear polymers (Jaguar HP 120 COS), and evaluate them against these design criteria. All four additives provide acceptable spreadability by shear thinning to η≈10−1Pa s at γ˙∼103s−1. Either the finite yield stress conferred by the microgels (σy≳10Pa) or the increase in low-shear viscosity provided by the linear polymer (η≳1Pa s at γ˙≲0.1s−1) give rise to acceptably low runoff. However, the formulation using the linear polymer shows a filament breakage time of τb≈1s in capillary rheology, which may result in stickiness and therefore a less than optimal hand feel.
Original languageEnglish
Pages (from-to)571-581
Number of pages11
JournalRheologica acta
Volume61
Issue number8-9
DOIs
Publication statusPublished - 5 Jul 2022

Keywords

  • cond-mat.soft
  • Hand sanitisers
  • Rheology
  • Microgels
  • Polymers

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