Rhodium-Catalyzed [2+2] Cycloaddition of Ynamides with Nitroalkenes

Donna L. Smith; Suresh Reddy Chidipudi; William R. Goundry; Hon Wai Lam

doi:10.1021/ol302259v

Rhodium-Catalyzed [2+2] Cycloaddition of Ynamides with Nitroalkenes

Donna L. Smith, Suresh Reddy Chidipudi, William R. Goundry, Hon Wai Lam

Research output: Contribution to journal › Article › peer-review

Abstract / Description of output

In the presence of a diene-ligated rhodium complex, ynamides and nitroalkenes undergo catalytic [2 + 2] cycloadditions to provide cyclobutenamides. The presence of sodium tetraphenylborate was found to be crucial for the reactions to proceed efficiently.

Original language	English
Pages (from-to)	4934-4937
Number of pages	4
Journal	Organic letters
Volume	14
Issue number	18
DOIs	https://doi.org/10.1021/ol302259v
Publication status	Published - 21 Sept 2012

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@article{78b910c2abfd48f49b3c98e4335625b1,

title = "Rhodium-Catalyzed [2+2] Cycloaddition of Ynamides with Nitroalkenes",

abstract = "In the presence of a diene-ligated rhodium complex, ynamides and nitroalkenes undergo catalytic [2 + 2] cycloadditions to provide cyclobutenamides. The presence of sodium tetraphenylborate was found to be crucial for the reactions to proceed efficiently.",

author = "Smith, {Donna L.} and Chidipudi, {Suresh Reddy} and Goundry, {William R.} and Lam, {Hon Wai}",

year = "2012",

month = sep,

day = "21",

doi = "10.1021/ol302259v",

language = "English",

volume = "14",

pages = "4934--4937",

journal = "Organic letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "18",

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TY - JOUR

T1 - Rhodium-Catalyzed [2+2] Cycloaddition of Ynamides with Nitroalkenes

AU - Smith, Donna L.

AU - Chidipudi, Suresh Reddy

AU - Goundry, William R.

AU - Lam, Hon Wai

PY - 2012/9/21

Y1 - 2012/9/21

N2 - In the presence of a diene-ligated rhodium complex, ynamides and nitroalkenes undergo catalytic [2 + 2] cycloadditions to provide cyclobutenamides. The presence of sodium tetraphenylborate was found to be crucial for the reactions to proceed efficiently.

AB - In the presence of a diene-ligated rhodium complex, ynamides and nitroalkenes undergo catalytic [2 + 2] cycloadditions to provide cyclobutenamides. The presence of sodium tetraphenylborate was found to be crucial for the reactions to proceed efficiently.

U2 - 10.1021/ol302259v

DO - 10.1021/ol302259v

M3 - Article

SN - 1523-7060

VL - 14

SP - 4934

EP - 4937

JO - Organic letters

JF - Organic letters

IS - 18

ER -

Rhodium-Catalyzed [2+2] Cycloaddition of Ynamides with Nitroalkenes

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