Rhodium-Catalyzed Annulation of Ynamides with Bifunctional Arylboron Reagents

Benoit Gourdet; Mairi E. Rudkin; Hon Wai Lam

doi:10.1021/ol100769p

Rhodium-Catalyzed Annulation of Ynamides with Bifunctional Arylboron Reagents

Benoit Gourdet, Mairi E. Rudkin, Hon Wai Lam

Research output: Contribution to journal › Article › peer-review

Abstract / Description of output

Annulation of ynamides with arylboronic acids or esters containing an electrophilic functional group at the ortho-position proceeds under the action of rhodium catalysis to generate 2-amidoindenols or 2-amidoindenes, usually with good regioselectivity,

Original language	English
Pages (from-to)	2554-2557
Number of pages	4
Journal	Organic letters
Volume	12
Issue number	11
DOIs	https://doi.org/10.1021/ol100769p
Publication status	Published - 4 Jun 2010

Keywords / Materials (for Non-textual outputs)

AZA-CLAISEN REARRANGEMENT
BOND-FORMING REACTIONS
STRAINED ALKENES
AQUEOUS-MEDIA
REGIOSELECTIVE CARBOCYCLIZATION
FACILE ROUTE
ALKYNES
ACIDS
INDENOLS
KETONES

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10.1021/ol100769p

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@article{dc0882f47b9f41259506f8191577dcb0,

title = "Rhodium-Catalyzed Annulation of Ynamides with Bifunctional Arylboron Reagents",

abstract = "Annulation of ynamides with arylboronic acids or esters containing an electrophilic functional group at the ortho-position proceeds under the action of rhodium catalysis to generate 2-amidoindenols or 2-amidoindenes, usually with good regioselectivity,",

keywords = "AZA-CLAISEN REARRANGEMENT, BOND-FORMING REACTIONS, STRAINED ALKENES, AQUEOUS-MEDIA, REGIOSELECTIVE CARBOCYCLIZATION, FACILE ROUTE, ALKYNES, ACIDS, INDENOLS, KETONES",

author = "Benoit Gourdet and Rudkin, {Mairi E.} and Lam, {Hon Wai}",

year = "2010",

month = jun,

day = "4",

doi = "10.1021/ol100769p",

language = "English",

volume = "12",

pages = "2554--2557",

journal = "Organic letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "11",

}

TY - JOUR

T1 - Rhodium-Catalyzed Annulation of Ynamides with Bifunctional Arylboron Reagents

AU - Gourdet, Benoit

AU - Rudkin, Mairi E.

AU - Lam, Hon Wai

PY - 2010/6/4

Y1 - 2010/6/4

N2 - Annulation of ynamides with arylboronic acids or esters containing an electrophilic functional group at the ortho-position proceeds under the action of rhodium catalysis to generate 2-amidoindenols or 2-amidoindenes, usually with good regioselectivity,

AB - Annulation of ynamides with arylboronic acids or esters containing an electrophilic functional group at the ortho-position proceeds under the action of rhodium catalysis to generate 2-amidoindenols or 2-amidoindenes, usually with good regioselectivity,

KW - AZA-CLAISEN REARRANGEMENT

KW - BOND-FORMING REACTIONS

KW - STRAINED ALKENES

KW - AQUEOUS-MEDIA

KW - REGIOSELECTIVE CARBOCYCLIZATION

KW - FACILE ROUTE

KW - ALKYNES

KW - ACIDS

KW - INDENOLS

KW - KETONES

UR - http://www.scopus.com/inward/record.url?scp=77953013396&partnerID=8YFLogxK

U2 - 10.1021/ol100769p

DO - 10.1021/ol100769p

M3 - Article

SN - 1523-7060

VL - 12

SP - 2554

EP - 2557

JO - Organic letters

JF - Organic letters

IS - 11

ER -

Rhodium-Catalyzed Annulation of Ynamides with Bifunctional Arylboron Reagents

Abstract / Description of output

Keywords / Materials (for Non-textual outputs)

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