TY - JOUR
T1 - Salicylaldoxime-Supported Nona- and Tetrametallic Fe-III Cages
AU - Brechin, Euan
AU - Mason, Kevin
AU - Prescimone, Alessandro
AU - Schau-Magnussen, Magnus
AU - Piligkos, Stergios
AU - Tasker, Peter
PY - 2013/6
Y1 - 2013/6
N2 - The syntheses, structures and magnetic properties of seven new iron complexes, [Fe4O2(sao)4(tacn)2]·2MeOH·H2O (1·2MeOH·H2O), [Fe4O2(Me-sao)4(tacn)2]·2MeCN (2·2MeCN), [Fe4O2(Etsao) 4(tacn)2]·MeOH (3·MeOH), [Fe9NaO4(Et-sao)6(hmp)8]·3MeCN·Et2O (4·3MeCN·Et2O), [Fe4(Et-sao)4(hmp)4]·Et-saoH2 (5·Et-saoH2), [Fe4(Ph-sao)4(hmp)4]·2MeCN (6·2MeCN) [Fe9O3(sao)(pdm)6(N3)7(H2O)] (7), stabilised with salicylaldoxime (saoH2) or derivatised salicylaldoxime (R-saoH2) ligands in conjunction with either 1,4,7-triazocyclononane (tacn), 2-(hydroxymethyl)pyridine (hmpH) or 2,6-pyridinedimethanol (pdmH2) are discussed.
AB - The syntheses, structures and magnetic properties of seven new iron complexes, [Fe4O2(sao)4(tacn)2]·2MeOH·H2O (1·2MeOH·H2O), [Fe4O2(Me-sao)4(tacn)2]·2MeCN (2·2MeCN), [Fe4O2(Etsao) 4(tacn)2]·MeOH (3·MeOH), [Fe9NaO4(Et-sao)6(hmp)8]·3MeCN·Et2O (4·3MeCN·Et2O), [Fe4(Et-sao)4(hmp)4]·Et-saoH2 (5·Et-saoH2), [Fe4(Ph-sao)4(hmp)4]·2MeCN (6·2MeCN) [Fe9O3(sao)(pdm)6(N3)7(H2O)] (7), stabilised with salicylaldoxime (saoH2) or derivatised salicylaldoxime (R-saoH2) ligands in conjunction with either 1,4,7-triazocyclononane (tacn), 2-(hydroxymethyl)pyridine (hmpH) or 2,6-pyridinedimethanol (pdmH2) are discussed.
U2 - 10.2174/1877944111303020002
DO - 10.2174/1877944111303020002
M3 - Article
SN - 1877-9441
VL - 3
SP - 76
EP - 85
JO - Current Inorganic Chemistry
JF - Current Inorganic Chemistry
IS - 2
ER -