Projects per year
Glassy polymers show "strain hardening": at constant extensional load, their flow first accelerates, then arrests. Recent experiments have found this to be accompanied by a striking and unexplained dip in the segmental relaxation time. Here we explain such behavior by combining a minimal model of flow-induced liquefaction of a glass with a description of the stress carried by strained polymers, creating a nonfactorable interplay between aging and strain-induced rejuvenation. Under constant load, liquefaction of segmental motion permits strong flow that creates polymer-borne stress. This slows the deformation enough for the segmental modes to revitrify, causing strain hardening.
|Number of pages||5|
|Journal||Physical Review Letters|
|Publication status||Published - 25 Jan 2012|
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- 2 Finished
Design Principles for New Soft Materials
Cates, M., Allen, R., Clegg, P., Evans, M., MacPhee, C., Marenduzzo, D. & Poon, W.
7/12/11 → 6/06/17
Edinbugrh Soft Matter and Statistical Physics Programme Grant Renewal
Cates, M., Poon, W., Ackland, G., Clegg, P., Evans, M., MacPhee, C. & Marenduzzo, D.
1/10/07 → 31/03/12