Single Crystal X-Ray Diffraction Study of Pressure and Temperature Induced Spin Trapping in a Bistable FeII Hofmann Framework

Gemma Turner, Fallyn Campbell, Stephen Anderson Moggach, Simon Parsons, Andres E. Goeta, Carmen Munoz, Jose Real

Research output: Contribution to journalArticlepeer-review

Abstract

High-pressure single crystal X-ray diffraction has been used to trap both the low-spin (LS) and high-spin (HS) states of the iron(II) Hofmann spin crossover framework, [FeII(pdm)(H2O) [Ag(CN)2]2·H2O, under identical experimental conditions, allowing the structural changes arising from the spin-transition to be deconvoluted from previously reported thermal effects.
Original languageEnglish
JournalAngewandte Chemie International Edition
Early online date28 Nov 2019
DOIs
Publication statusE-pub ahead of print - 28 Nov 2019

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