Abstract
We develop a slender-body theory for plasmonic resonance of slender metallic nanoparticles, focusing on a general class of axisymmetric geometries with locally paraboloidal tips. We adopt a modal approach where one first solves the plasmonic eigenvalue problem, a geometric spectral problem which governs the surface-plasmon modes of the particle; then, the latter modes are used, in conjunction with spectral-decomposition, to analyse localized-surface-plasmon resonance in the quasi-static limit. We show that the permittivity eigenvalues of the axisymmetric modes are strongly singular in the slenderness parameter, implying widely tunable, high-quality-factor, resonances in the near-infrared regime. For that family of modes, we use matched asymptotics to derive an effective eigenvalue problem, a singular non-local Sturm–Liouville problem, where the lumped one-dimensional eigenfunctions represent axial voltage profiles (or charge line densities). We solve the effective eigenvalue problem in closed form for a prolate spheroid and numerically, by expanding the eigenfunctions in Legendre polynomials, for arbitrarily shaped particles. We apply the theory to plane-wave illumination in order to elucidate the excitation of multiple resonances in the case of non-spheroidal particles.
Original language | English |
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Number of pages | 20 |
Journal | Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences |
Volume | 475 |
Issue number | 2229 |
DOIs | |
Publication status | Published - 18 Sept 2019 |