Solubility of gases and liquids in glassy polymers

M.G. De Angelis; G.C. Sarti

doi:10.1146/annurev-chembioeng-061010-114247

Solubility of gases and liquids in glassy polymers

M.G. De Angelis, G.C. Sarti

School of Engineering

Research output: Contribution to journal › Article › peer-review

Abstract / Description of output

This review discusses a macroscopic thermodynamic procedure to calculate the solubility of gases, vapors, and liquids in glassy polymers that is based on the general procedure provided by the nonequilibrium thermodynamics for glassy polymers (NET-GP) method. Several examples are presented using various nonequilibrium (NE) models including lattice fluid (NELF), statistical associating fluid theory (NE-SAFT), and perturbed hard sphere chain (NE-PHSC). Particular applications illustrate the calculation of infinite-dilution solubility coefficients in different glassy polymers and the prediction of solubility isotherms for different gases and vapors in pure polymers as well as in polymer blends. The determination of model parameters is discussed, and the predictive abilities of the models are illustrated. Attention is also given to the solubility of gas mixtures and solubility isotherms in nanocomposite mixed matrices. The fractional free volume determined from solubility data can be used to correlate solute diffusivities in mixed matrices. © Copyright 2011 by Annual Reviews. All rights reserved.

Original language	English
Pages (from-to)	97-120
Number of pages	24
Journal	Annual Review of Chemical and Biomolecular Engineering
Volume	2
DOIs	https://doi.org/10.1146/annurev-chembioeng-061010-114247
Publication status	Published - 2011

Keywords / Materials (for Non-textual outputs)

Diffusivities
Fractional free volume
Glassy polymers
Model parameters
Non equilibrium
Non equilibrium thermodynamics
Non-equilibrium thermodynamic model
Perturbed hard spheres
Predictive abilities
Pure polymers
Solubility data
Solubility isotherm
Statistical associating fluid theory
Isotherms
Nanocomposites
Polymer blends
Sorption
Spheres
Vapors
Solubility
polymer
chemical model
chemistry
gas
molecular weight
phase transition
review
solubility
solution and solubility
thermodynamics
Gases
Models
Chemical
Molecular Weight
Phase Transition
Polymers
Solutions
Thermodynamics

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10.1146/annurev-chembioeng-061010-114247

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@article{3c15ec08f60e4440ac8c7f95cef021ab,

title = "Solubility of gases and liquids in glassy polymers",

abstract = "This review discusses a macroscopic thermodynamic procedure to calculate the solubility of gases, vapors, and liquids in glassy polymers that is based on the general procedure provided by the nonequilibrium thermodynamics for glassy polymers (NET-GP) method. Several examples are presented using various nonequilibrium (NE) models including lattice fluid (NELF), statistical associating fluid theory (NE-SAFT), and perturbed hard sphere chain (NE-PHSC). Particular applications illustrate the calculation of infinite-dilution solubility coefficients in different glassy polymers and the prediction of solubility isotherms for different gases and vapors in pure polymers as well as in polymer blends. The determination of model parameters is discussed, and the predictive abilities of the models are illustrated. Attention is also given to the solubility of gas mixtures and solubility isotherms in nanocomposite mixed matrices. The fractional free volume determined from solubility data can be used to correlate solute diffusivities in mixed matrices. {\textcopyright} Copyright 2011 by Annual Reviews. All rights reserved.",

keywords = "Diffusivities, Fractional free volume, Glassy polymers, Model parameters, Non equilibrium, Non equilibrium thermodynamics, Non-equilibrium thermodynamic model, Perturbed hard spheres, Predictive abilities, Pure polymers, Solubility data, Solubility isotherm, Statistical associating fluid theory, Isotherms, Nanocomposites, Polymer blends, Sorption, Spheres, Vapors, Solubility, polymer, chemical model, chemistry, gas, molecular weight, phase transition, review, solubility, solution and solubility, thermodynamics, Gases, Models, Chemical, Molecular Weight, Phase Transition, Polymers, Solutions, Thermodynamics",

author = "{De Angelis}, M.G. and G.C. Sarti",

note = "cited By 56",

year = "2011",

doi = "10.1146/annurev-chembioeng-061010-114247",

language = "English",

volume = "2",

pages = "97--120",

journal = "Annual Review of Chemical and Biomolecular Engineering",

issn = "1947-5446",

publisher = "Annual Reviews Inc.",

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T1 - Solubility of gases and liquids in glassy polymers

AU - De Angelis, M.G.

AU - Sarti, G.C.

N1 - cited By 56

PY - 2011

Y1 - 2011

N2 - This review discusses a macroscopic thermodynamic procedure to calculate the solubility of gases, vapors, and liquids in glassy polymers that is based on the general procedure provided by the nonequilibrium thermodynamics for glassy polymers (NET-GP) method. Several examples are presented using various nonequilibrium (NE) models including lattice fluid (NELF), statistical associating fluid theory (NE-SAFT), and perturbed hard sphere chain (NE-PHSC). Particular applications illustrate the calculation of infinite-dilution solubility coefficients in different glassy polymers and the prediction of solubility isotherms for different gases and vapors in pure polymers as well as in polymer blends. The determination of model parameters is discussed, and the predictive abilities of the models are illustrated. Attention is also given to the solubility of gas mixtures and solubility isotherms in nanocomposite mixed matrices. The fractional free volume determined from solubility data can be used to correlate solute diffusivities in mixed matrices. © Copyright 2011 by Annual Reviews. All rights reserved.

AB - This review discusses a macroscopic thermodynamic procedure to calculate the solubility of gases, vapors, and liquids in glassy polymers that is based on the general procedure provided by the nonequilibrium thermodynamics for glassy polymers (NET-GP) method. Several examples are presented using various nonequilibrium (NE) models including lattice fluid (NELF), statistical associating fluid theory (NE-SAFT), and perturbed hard sphere chain (NE-PHSC). Particular applications illustrate the calculation of infinite-dilution solubility coefficients in different glassy polymers and the prediction of solubility isotherms for different gases and vapors in pure polymers as well as in polymer blends. The determination of model parameters is discussed, and the predictive abilities of the models are illustrated. Attention is also given to the solubility of gas mixtures and solubility isotherms in nanocomposite mixed matrices. The fractional free volume determined from solubility data can be used to correlate solute diffusivities in mixed matrices. © Copyright 2011 by Annual Reviews. All rights reserved.

KW - Diffusivities

KW - Fractional free volume

KW - Glassy polymers

KW - Model parameters

KW - Non equilibrium

KW - Non equilibrium thermodynamics

KW - Non-equilibrium thermodynamic model

KW - Perturbed hard spheres

KW - Predictive abilities

KW - Pure polymers

KW - Solubility data

KW - Solubility isotherm

KW - Statistical associating fluid theory

KW - Isotherms

KW - Nanocomposites

KW - Polymer blends

KW - Sorption

KW - Spheres

KW - Vapors

KW - Solubility

KW - polymer

KW - chemical model

KW - chemistry

KW - gas

KW - molecular weight

KW - phase transition

KW - review

KW - solubility

KW - solution and solubility

KW - thermodynamics

KW - Gases

KW - Models

KW - Chemical

KW - Molecular Weight

KW - Phase Transition

KW - Polymers

KW - Solutions

KW - Thermodynamics

U2 - 10.1146/annurev-chembioeng-061010-114247

DO - 10.1146/annurev-chembioeng-061010-114247

M3 - Article

SN - 1947-5446

VL - 2

SP - 97

EP - 120

JO - Annual Review of Chemical and Biomolecular Engineering

JF - Annual Review of Chemical and Biomolecular Engineering

ER -

Solubility of gases and liquids in glassy polymers

Abstract / Description of output

Keywords / Materials (for Non-textual outputs)

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