Stabilization of cubic Sr2FeMoO6 through topochemical reduction

Daniel D. Taylor, Nathaniel J. Schreiber, Craig M. Brown, Angel M. Arevalo-Lopez, Efrain E. Rodriguez*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

Sr2FeMoO6 has been extensively studied for application in spintronic devices. Through the topochemical de-intercalation of oxygen anions with metal hydride reduction, we demonstrate that the high temperature cubic phase is stabilized, at room temperature, whilst leaving the magnetic ordering intact. Synchrotron X-ray and neutron powder diffraction were used to characterize the structure and stoichiometry of the reduced oxide.

Original languageEnglish
Pages (from-to)12201-12204
Number of pages4
JournalChemical Communications
Volume51
Issue number61
DOIs
Publication statusPublished - 7 Aug 2015

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