Structural and magnetic properties of the binuclear [Co-2{(OPPh2)(2)N}(4)] complex: Ferromagnetic coupling between the two S=3/2 Co(II) ions

Eleftherios Ferentinos; Spyros D. Chatziefthimiou; Neil Robertson; Panayotis Kyritsis

doi:10.1016/j.inoche.2009.05.001

Structural and magnetic properties of the binuclear [Co-2{(OPPh2)(2)N}(4)] complex: Ferromagnetic coupling between the two S=3/2 Co(II) ions

Eleftherios Ferentinos, Spyros D. Chatziefthimiou, Neil Robertson, Panayotis Kyritsis

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction between Co(II) and the deprotonated tetraphenylimidodiphosphinic acid, [(OPPh2)(2)N](-), afforded a binuclear [Co-2{(OPPh2)(2)N}(4)] complex, as revealed by X-ray crystallography. The structure contains two monometallic biconnective I(OPPh2)2N]- ligands, with an averaged Co-O bond length of 2.008 angstrom. The other two [(OPPh2)(2)N](-) act as bimetallic triconnective ligands, forming two oxygen atom bridges, with the four Co-O(bridging) distances averaged at 2.155 angstrom, and the two Co-O(non-bridging) distances at 1.973 angstrom. The two approximately trigonal bipyramidal Co(II) ions are at a Co center dot center dot center dot Co distance of 3.301 angstrom. The analysis of the magnetic properties of [Co-2{(OPPh2)(2)N}(4)] is consistent with an unusual ferromagnetic interaction, in a binuclear Co(II) system, between the two S = 3/2 Co(II) ions. (C) 2009 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	615-618
Number of pages	4
Journal	Inorganic chemistry communications
Volume	12
Issue number	7
DOIs	https://doi.org/10.1016/j.inoche.2009.05.001
Publication status	Published - Jul 2009

Keywords / Materials (for Non-textual outputs)

Cobalt
Tetraphenylimidodiphosphinic acid
Binuclear complex
Ferromagnetic coupling
LUMINESCENT LANTHANIDE COMPLEXES
X-RAY-STRUCTURE
DICOBALT II-II
CRYSTAL-STRUCTURES
TETRAORGANODICHALCOGENOIMIDODIPHOSPHINATO-LIGANDS
COBALT(II) COMPLEXES
MOLECULAR-STRUCTURE
SPECTROSCOPIC CHARACTERIZATION
MANGANESE(II) COMPLEXES
DOT CH2CL2

Access to Document

10.1016/j.inoche.2009.05.001

Cite this

@article{5938291ae164464195834421f3888be4,

title = "Structural and magnetic properties of the binuclear [Co-2{(OPPh2)(2)N}(4)] complex: Ferromagnetic coupling between the two S=3/2 Co(II) ions",

abstract = "The reaction between Co(II) and the deprotonated tetraphenylimidodiphosphinic acid, [(OPPh2)(2)N](-), afforded a binuclear [Co-2{(OPPh2)(2)N}(4)] complex, as revealed by X-ray crystallography. The structure contains two monometallic biconnective I(OPPh2)2N]- ligands, with an averaged Co-O bond length of 2.008 angstrom. The other two [(OPPh2)(2)N](-) act as bimetallic triconnective ligands, forming two oxygen atom bridges, with the four Co-O(bridging) distances averaged at 2.155 angstrom, and the two Co-O(non-bridging) distances at 1.973 angstrom. The two approximately trigonal bipyramidal Co(II) ions are at a Co center dot center dot center dot Co distance of 3.301 angstrom. The analysis of the magnetic properties of [Co-2{(OPPh2)(2)N}(4)] is consistent with an unusual ferromagnetic interaction, in a binuclear Co(II) system, between the two S = 3/2 Co(II) ions. (C) 2009 Elsevier B.V. All rights reserved.",

keywords = "Cobalt, Tetraphenylimidodiphosphinic acid, Binuclear complex, Ferromagnetic coupling, LUMINESCENT LANTHANIDE COMPLEXES, X-RAY-STRUCTURE, DICOBALT II-II, CRYSTAL-STRUCTURES, TETRAORGANODICHALCOGENOIMIDODIPHOSPHINATO-LIGANDS, COBALT(II) COMPLEXES, MOLECULAR-STRUCTURE, SPECTROSCOPIC CHARACTERIZATION, MANGANESE(II) COMPLEXES, DOT CH2CL2",

author = "Eleftherios Ferentinos and Chatziefthimiou, {Spyros D.} and Neil Robertson and Panayotis Kyritsis",

year = "2009",

month = jul,

doi = "10.1016/j.inoche.2009.05.001",

language = "English",

volume = "12",

pages = "615--618",

journal = "Inorganic chemistry communications",

issn = "1387-7003",

publisher = "Elsevier",

number = "7",

}

TY - JOUR

T1 - Structural and magnetic properties of the binuclear [Co-2{(OPPh2)(2)N}(4)] complex: Ferromagnetic coupling between the two S=3/2 Co(II) ions

AU - Ferentinos, Eleftherios

AU - Chatziefthimiou, Spyros D.

AU - Robertson, Neil

AU - Kyritsis, Panayotis

PY - 2009/7

Y1 - 2009/7

N2 - The reaction between Co(II) and the deprotonated tetraphenylimidodiphosphinic acid, [(OPPh2)(2)N](-), afforded a binuclear [Co-2{(OPPh2)(2)N}(4)] complex, as revealed by X-ray crystallography. The structure contains two monometallic biconnective I(OPPh2)2N]- ligands, with an averaged Co-O bond length of 2.008 angstrom. The other two [(OPPh2)(2)N](-) act as bimetallic triconnective ligands, forming two oxygen atom bridges, with the four Co-O(bridging) distances averaged at 2.155 angstrom, and the two Co-O(non-bridging) distances at 1.973 angstrom. The two approximately trigonal bipyramidal Co(II) ions are at a Co center dot center dot center dot Co distance of 3.301 angstrom. The analysis of the magnetic properties of [Co-2{(OPPh2)(2)N}(4)] is consistent with an unusual ferromagnetic interaction, in a binuclear Co(II) system, between the two S = 3/2 Co(II) ions. (C) 2009 Elsevier B.V. All rights reserved.

AB - The reaction between Co(II) and the deprotonated tetraphenylimidodiphosphinic acid, [(OPPh2)(2)N](-), afforded a binuclear [Co-2{(OPPh2)(2)N}(4)] complex, as revealed by X-ray crystallography. The structure contains two monometallic biconnective I(OPPh2)2N]- ligands, with an averaged Co-O bond length of 2.008 angstrom. The other two [(OPPh2)(2)N](-) act as bimetallic triconnective ligands, forming two oxygen atom bridges, with the four Co-O(bridging) distances averaged at 2.155 angstrom, and the two Co-O(non-bridging) distances at 1.973 angstrom. The two approximately trigonal bipyramidal Co(II) ions are at a Co center dot center dot center dot Co distance of 3.301 angstrom. The analysis of the magnetic properties of [Co-2{(OPPh2)(2)N}(4)] is consistent with an unusual ferromagnetic interaction, in a binuclear Co(II) system, between the two S = 3/2 Co(II) ions. (C) 2009 Elsevier B.V. All rights reserved.

KW - Cobalt

KW - Tetraphenylimidodiphosphinic acid

KW - Binuclear complex

KW - Ferromagnetic coupling

KW - LUMINESCENT LANTHANIDE COMPLEXES

KW - X-RAY-STRUCTURE

KW - DICOBALT II-II

KW - CRYSTAL-STRUCTURES

KW - TETRAORGANODICHALCOGENOIMIDODIPHOSPHINATO-LIGANDS

KW - COBALT(II) COMPLEXES

KW - MOLECULAR-STRUCTURE

KW - SPECTROSCOPIC CHARACTERIZATION

KW - MANGANESE(II) COMPLEXES

KW - DOT CH2CL2

UR - http://www.scopus.com/inward/record.url?scp=67649494310&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2009.05.001

DO - 10.1016/j.inoche.2009.05.001

M3 - Article

SN - 1387-7003

VL - 12

SP - 615

EP - 618

JO - Inorganic chemistry communications

JF - Inorganic chemistry communications

IS - 7

ER -

Structural and magnetic properties of the binuclear [Co-2{(OPPh2)(2)N}(4)] complex: Ferromagnetic coupling between the two S=3/2 Co(II) ions

Abstract

Keywords / Materials (for Non-textual outputs)

Access to Document

Other files and links

Fingerprint

Cite this