Supertetrahedral decametallic Ni(II) clusters directed by mu(6)-tris-alkoxides

R  Shaw; I S  Tidmarsh; R H  Laye; B  Breeze; M  Helliwell; E K  Brechin; S L  Heath; M  Murrie; S  Ochsenbein; H U  Gudel; E J L  McInnes

doi:10.1039/b403876b

Supertetrahedral decametallic Ni(II) clusters directed by mu(6)-tris-alkoxides

R Shaw, I S Tidmarsh, R H Laye, B Breeze, M Helliwell, E K Brechin, S L Heath, M Murrie, S Ochsenbein, H U Gudel, E J L McInnes

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

We report the syntheses, structures and magnetic properties of two decametallic Ni(II) clusters with unprecedented supertetrahedral cores, stabilised by the (hitherto unobserved) mu(6)-coordination modes of the tris-alkoxides {MeC(CH2O)(3)}(3)(-) and {C6H9O3}(3-).

Original language	English
Pages (from-to)	1418-1419
Number of pages	2
Journal	Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/b403876b
Publication status	Published - 21 Jun 2004

Keywords / Materials (for Non-textual outputs)

MAGNETIC-PROPERTIES
OXIDES

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10.1039/b403876b

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title = "Supertetrahedral decametallic Ni(II) clusters directed by mu(6)-tris-alkoxides",

abstract = "We report the syntheses, structures and magnetic properties of two decametallic Ni(II) clusters with unprecedented supertetrahedral cores, stabilised by the (hitherto unobserved) mu(6)-coordination modes of the tris-alkoxides \{MeC(CH2O)(3)\}(3)(-) and \{C6H9O3\}(3-).",

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author = "R Shaw and Tidmarsh, \{I S\} and Laye, \{R H\} and B Breeze and M Helliwell and Brechin, \{E K\} and Heath, \{S L\} and M Murrie and S Ochsenbein and Gudel, \{H U\} and McInnes, \{E J L\}",

year = "2004",

month = jun,

day = "21",

doi = "10.1039/b403876b",

language = "English",

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publisher = "Royal Society of Chemistry",

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T1 - Supertetrahedral decametallic Ni(II) clusters directed by mu(6)-tris-alkoxides

AU - Shaw, R

AU - Tidmarsh, I S

AU - Laye, R H

AU - Breeze, B

AU - Helliwell, M

AU - Brechin, E K

AU - Heath, S L

AU - Murrie, M

AU - Ochsenbein, S

AU - Gudel, H U

AU - McInnes, E J L

PY - 2004/6/21

Y1 - 2004/6/21

N2 - We report the syntheses, structures and magnetic properties of two decametallic Ni(II) clusters with unprecedented supertetrahedral cores, stabilised by the (hitherto unobserved) mu(6)-coordination modes of the tris-alkoxides {MeC(CH2O)(3)}(3)(-) and {C6H9O3}(3-).

AB - We report the syntheses, structures and magnetic properties of two decametallic Ni(II) clusters with unprecedented supertetrahedral cores, stabilised by the (hitherto unobserved) mu(6)-coordination modes of the tris-alkoxides {MeC(CH2O)(3)}(3)(-) and {C6H9O3}(3-).

KW - MAGNETIC-PROPERTIES

KW - OXIDES

U2 - 10.1039/b403876b

DO - 10.1039/b403876b

M3 - Article

SN - 1359-7345

SP - 1418

EP - 1419

JO - Chemical Communications

JF - Chemical Communications

IS - 12

ER -

Supertetrahedral decametallic Ni(II) clusters directed by mu(6)-tris-alkoxides

Abstract

Keywords / Materials (for Non-textual outputs)

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