Synthesis and characterisation of a mixed-valence Mn-13 complex with S-6 symmetry by using 2-phenoxybenzoate

Alan Ferguson, Katrina Thomson, Andrew Parkin, Paul Cooper, Constantinos J. Milios, Euan K. Brechin, Mark Murrie

Research output: Contribution to journalArticlepeer-review

Abstract

The synthesis, structure and magnetic properties of [Mn13O8(OEt)(6)(O2CC6H4OPh)(12)] are reported as the first example of a high nuclearity manganese complex with 2-phenoxybenzoate: the complex possesses S-6 symmetry and an S = 11/2 ground state.

Original languageEnglish
Pages (from-to)728-730
Number of pages3
JournalDalton Transactions
Issue number7
DOIs
Publication statusPublished - 2007

Keywords

  • SINGLE-MOLECULE MAGNETS
  • SPIN

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