Synthesis and characterization of [PPh(4)][M(diod)(2)], M=Ni, Pd, Cu or Au; Crystal structure of [PPh(4)][Cu(diod)(2)]

C F  Cleary; N  Robertson; M  Takahashi; A E  Underhill; D E  Hibbs; M B  Hursthouse; K M A  Malik

Synthesis and characterization of [PPh(4)][M(diod)(2)], M=Ni, Pd, Cu or Au; Crystal structure of [PPh(4)][Cu(diod)(2)]

C F Cleary, N Robertson, M Takahashi, A E Underhill, D E Hibbs, M B Hursthouse, K M A Malik

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The complexes [P(C6H5)(4)][M(diod)(2)][where M = Ni, Pd, Cu or Au (2a, b, c, d)] have been prepared and characterized spectroscopically, electrochemically and by X-ray structure determination for 2c. Preparation of 2d involved isolation of an intermediate complex with only one died ligand. The Ni complex 2a forms semiconducting charge transfer complexes with TTF and BEDT-TTF. Copyright (C) 1997 Elsevier Science Ltd.

Original language	English
Pages (from-to)	1111-1117
Number of pages	7
Journal	Polyhedron
Volume	16
Issue number	7
Publication status	Published - 1997

Keywords / Materials (for Non-textual outputs)

dithiolene
crystal structure
charge-transfer salt
COMPLEXES
1,2-DITHIOLENE
LIGANDS
METAL
SALTS

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@article{68177128710446469a5b43817b798839,

title = "Synthesis and characterization of [PPh(4)][M(diod)(2)], M=Ni, Pd, Cu or Au; Crystal structure of [PPh(4)][Cu(diod)(2)]",

abstract = "The complexes [P(C6H5)(4)][M(diod)(2)][where M = Ni, Pd, Cu or Au (2a, b, c, d)] have been prepared and characterized spectroscopically, electrochemically and by X-ray structure determination for 2c. Preparation of 2d involved isolation of an intermediate complex with only one died ligand. The Ni complex 2a forms semiconducting charge transfer complexes with TTF and BEDT-TTF. Copyright (C) 1997 Elsevier Science Ltd.",

keywords = "dithiolene, crystal structure, charge-transfer salt, COMPLEXES, 1,2-DITHIOLENE, LIGANDS, METAL, SALTS",

author = "Cleary, {C F} and N Robertson and M Takahashi and Underhill, {A E} and Hibbs, {D E} and Hursthouse, {M B} and Malik, {K M A}",

year = "1997",

language = "English",

volume = "16",

pages = "1111--1117",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Pergamon Press",

number = "7",

}

TY - JOUR

T1 - Synthesis and characterization of [PPh(4)][M(diod)(2)], M=Ni, Pd, Cu or Au; Crystal structure of [PPh(4)][Cu(diod)(2)]

AU - Cleary, C F

AU - Robertson, N

AU - Takahashi, M

AU - Underhill, A E

AU - Hibbs, D E

AU - Hursthouse, M B

AU - Malik, K M A

PY - 1997

Y1 - 1997

N2 - The complexes [P(C6H5)(4)][M(diod)(2)][where M = Ni, Pd, Cu or Au (2a, b, c, d)] have been prepared and characterized spectroscopically, electrochemically and by X-ray structure determination for 2c. Preparation of 2d involved isolation of an intermediate complex with only one died ligand. The Ni complex 2a forms semiconducting charge transfer complexes with TTF and BEDT-TTF. Copyright (C) 1997 Elsevier Science Ltd.

AB - The complexes [P(C6H5)(4)][M(diod)(2)][where M = Ni, Pd, Cu or Au (2a, b, c, d)] have been prepared and characterized spectroscopically, electrochemically and by X-ray structure determination for 2c. Preparation of 2d involved isolation of an intermediate complex with only one died ligand. The Ni complex 2a forms semiconducting charge transfer complexes with TTF and BEDT-TTF. Copyright (C) 1997 Elsevier Science Ltd.

KW - dithiolene

KW - crystal structure

KW - charge-transfer salt

KW - COMPLEXES

KW - 1,2-DITHIOLENE

KW - LIGANDS

KW - METAL

KW - SALTS

M3 - Article

SN - 0277-5387

VL - 16

SP - 1111

EP - 1117

JO - Polyhedron

JF - Polyhedron

IS - 7

ER -

Synthesis and characterization of [PPh(4)][M(diod)(2)], M=Ni, Pd, Cu or Au; Crystal structure of [PPh(4)][Cu(diod)(2)]

Abstract

Keywords / Materials (for Non-textual outputs)

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