Synthesis and structure of Pd(II) complexes of 1,2,3-triphenylguanidine

N Mincheva, T Todorov, O Angelova, PJ Bailey, M Mitewa*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

The formation of two complexes by reaction of [PdCl4](2-) with 1,2,3-triphenylguanidine (PhNH)(2)C=NPh under different metal/ligand ratios has been observed and the structure of the complex [(1,2,3-triphenylguanidine)(2)PdCl2] has been determined by X-ray diffraction methods. The ligands are coordinated as neutral monodentate molecules to the metal centre through their imine nitrogen atoms. The second Pd(II) complex is [Pd(1,2,3-triphenylguanidine)(4)](2+) and was isolated by precipitation with ClO4-.

Original languageEnglish
Pages (from-to)169-176
Number of pages8
JournalJournal of coordination chemistry
Volume50
Issue number2
Publication statusPublished - 2000

Keywords

  • 1,2,3-triphenylguanidine
  • Pd(II) complexes
  • X-ray structure
  • CRYSTAL-STRUCTURES
  • METAL
  • COORDINATION
  • PLATINUM(II)
  • LIGANDS
  • DIMER

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