Synthesis and structure of Pd(II) complexes of 1,2,3-triphenylguanidine

N Mincheva; T Todorov; O Angelova; PJ Bailey; M Mitewa

Synthesis and structure of Pd(II) complexes of 1,2,3-triphenylguanidine

N Mincheva, T Todorov, O Angelova, PJ Bailey, M Mitewa^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The formation of two complexes by reaction of [PdCl4](2-) with 1,2,3-triphenylguanidine (PhNH)(2)C=NPh under different metal/ligand ratios has been observed and the structure of the complex [(1,2,3-triphenylguanidine)(2)PdCl2] has been determined by X-ray diffraction methods. The ligands are coordinated as neutral monodentate molecules to the metal centre through their imine nitrogen atoms. The second Pd(II) complex is [Pd(1,2,3-triphenylguanidine)(4)](2+) and was isolated by precipitation with ClO4-.

Original language	English
Pages (from-to)	169-176
Number of pages	8
Journal	Journal of coordination chemistry
Volume	50
Issue number	2
Publication status	Published - 2000

Keywords / Materials (for Non-textual outputs)

1,2,3-triphenylguanidine
Pd(II) complexes
X-ray structure
CRYSTAL-STRUCTURES
METAL
COORDINATION
PLATINUM(II)
LIGANDS
DIMER

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@article{8613840b32b14b4697437350bc777e8c,

title = "Synthesis and structure of Pd(II) complexes of 1,2,3-triphenylguanidine",

abstract = "The formation of two complexes by reaction of [PdCl4](2-) with 1,2,3-triphenylguanidine (PhNH)(2)C=NPh under different metal/ligand ratios has been observed and the structure of the complex [(1,2,3-triphenylguanidine)(2)PdCl2] has been determined by X-ray diffraction methods. The ligands are coordinated as neutral monodentate molecules to the metal centre through their imine nitrogen atoms. The second Pd(II) complex is [Pd(1,2,3-triphenylguanidine)(4)](2+) and was isolated by precipitation with ClO4-.",

keywords = "1,2,3-triphenylguanidine, Pd(II) complexes, X-ray structure, CRYSTAL-STRUCTURES, METAL, COORDINATION, PLATINUM(II), LIGANDS, DIMER",

author = "N Mincheva and T Todorov and O Angelova and PJ Bailey and M Mitewa",

year = "2000",

language = "English",

volume = "50",

pages = "169--176",

journal = "Journal of coordination chemistry",

issn = "0095-8972",

publisher = "Taylor & Francis",

number = "2",

}

TY - JOUR

T1 - Synthesis and structure of Pd(II) complexes of 1,2,3-triphenylguanidine

AU - Mincheva, N

AU - Todorov, T

AU - Angelova, O

AU - Bailey, PJ

AU - Mitewa, M

PY - 2000

Y1 - 2000

N2 - The formation of two complexes by reaction of [PdCl4](2-) with 1,2,3-triphenylguanidine (PhNH)(2)C=NPh under different metal/ligand ratios has been observed and the structure of the complex [(1,2,3-triphenylguanidine)(2)PdCl2] has been determined by X-ray diffraction methods. The ligands are coordinated as neutral monodentate molecules to the metal centre through their imine nitrogen atoms. The second Pd(II) complex is [Pd(1,2,3-triphenylguanidine)(4)](2+) and was isolated by precipitation with ClO4-.

AB - The formation of two complexes by reaction of [PdCl4](2-) with 1,2,3-triphenylguanidine (PhNH)(2)C=NPh under different metal/ligand ratios has been observed and the structure of the complex [(1,2,3-triphenylguanidine)(2)PdCl2] has been determined by X-ray diffraction methods. The ligands are coordinated as neutral monodentate molecules to the metal centre through their imine nitrogen atoms. The second Pd(II) complex is [Pd(1,2,3-triphenylguanidine)(4)](2+) and was isolated by precipitation with ClO4-.

KW - 1,2,3-triphenylguanidine

KW - Pd(II) complexes

KW - X-ray structure

KW - CRYSTAL-STRUCTURES

KW - METAL

KW - COORDINATION

KW - PLATINUM(II)

KW - LIGANDS

KW - DIMER

M3 - Article

SN - 0095-8972

VL - 50

SP - 169

EP - 176

JO - Journal of coordination chemistry

JF - Journal of coordination chemistry

IS - 2

ER -

Synthesis and structure of Pd(II) complexes of 1,2,3-triphenylguanidine

Abstract

Keywords / Materials (for Non-textual outputs)

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