Synthesis and structure of [Sb{(Pr(i)N)(2)CNHPr(i)}{(Pr(i)N)(2)CNPr(i)}]; A distorted trigonal-bipyramidal antimony(III) complex with a helical hydrogen-bond network

P J  Bailey; R O  Gould; C N  Harmer; S  Pace; A  Steiner; D S  Wright

Synthesis and structure of [Sb{(Pr(i)N)(2)CNHPr(i)}{(Pr(i)N)(2)CNPr(i)}]; A distorted trigonal-bipyramidal antimony(III) complex with a helical hydrogen-bond network

P J Bailey, R O Gould, C N Harmer, S Pace, A Steiner, D S Wright

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract / Description of output

1,2,3-Triisopropylguanidine [((PrNH)-N-i)(2)C=NPri], reacts with antimony tris(dimethylamide) [Sb(NMe2)(3)] to provide [Sb(((PrN)-N-i)(2)CNHPri]{((PrN)-N-i)(2)CNPri}] 1, a heavily distorted trigonal-bipyramidal complex in which the Sb is chelated by a [C(NPri)(3)](2-) dianion and a [((PrN)-N-i)(2)CNHPri](-) monoanion; in the solid state the complexes form helices by N-H ... N hydrogen bonding of the single proton.

Original language	English
Pages (from-to)	1161-1162
Number of pages	2
Journal	Chemical Communications
Issue number	13
Publication status	Published - 7 Jul 1997

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@article{c0d107f5db7e4498a617d418b8d7c6fe,

title = "Synthesis and structure of [Sb{(Pr(i)N)(2)CNHPr(i)}{(Pr(i)N)(2)CNPr(i)}]; A distorted trigonal-bipyramidal antimony(III) complex with a helical hydrogen-bond network",

abstract = "1,2,3-Triisopropylguanidine [((PrNH)-N-i)(2)C=NPri], reacts with antimony tris(dimethylamide) [Sb(NMe2)(3)] to provide [Sb(((PrN)-N-i)(2)CNHPri]{((PrN)-N-i)(2)CNPri}] 1, a heavily distorted trigonal-bipyramidal complex in which the Sb is chelated by a [C(NPri)(3)](2-) dianion and a [((PrN)-N-i)(2)CNHPri](-) monoanion; in the solid state the complexes form helices by N-H ... N hydrogen bonding of the single proton.",

author = "Bailey, {P J} and Gould, {R O} and Harmer, {C N} and S Pace and A Steiner and Wright, {D S}",

year = "1997",

month = jul,

day = "7",

language = "English",

pages = "1161--1162",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "13",

}

TY - JOUR

T1 - Synthesis and structure of [Sb{(Pr(i)N)(2)CNHPr(i)}{(Pr(i)N)(2)CNPr(i)}]; A distorted trigonal-bipyramidal antimony(III) complex with a helical hydrogen-bond network

AU - Bailey, P J

AU - Gould, R O

AU - Harmer, C N

AU - Pace, S

AU - Steiner, A

AU - Wright, D S

PY - 1997/7/7

Y1 - 1997/7/7

N2 - 1,2,3-Triisopropylguanidine [((PrNH)-N-i)(2)C=NPri], reacts with antimony tris(dimethylamide) [Sb(NMe2)(3)] to provide [Sb(((PrN)-N-i)(2)CNHPri]{((PrN)-N-i)(2)CNPri}] 1, a heavily distorted trigonal-bipyramidal complex in which the Sb is chelated by a [C(NPri)(3)](2-) dianion and a [((PrN)-N-i)(2)CNHPri](-) monoanion; in the solid state the complexes form helices by N-H ... N hydrogen bonding of the single proton.

AB - 1,2,3-Triisopropylguanidine [((PrNH)-N-i)(2)C=NPri], reacts with antimony tris(dimethylamide) [Sb(NMe2)(3)] to provide [Sb(((PrN)-N-i)(2)CNHPri]{((PrN)-N-i)(2)CNPri}] 1, a heavily distorted trigonal-bipyramidal complex in which the Sb is chelated by a [C(NPri)(3)](2-) dianion and a [((PrN)-N-i)(2)CNHPri](-) monoanion; in the solid state the complexes form helices by N-H ... N hydrogen bonding of the single proton.

M3 - Article

SN - 1359-7345

SP - 1161

EP - 1162

JO - Chemical Communications

JF - Chemical Communications

IS - 13

ER -

Synthesis and structure of [Sb{(Pr(i)N)(2)CNHPr(i)}{(Pr(i)N)(2)CNPr(i)}]; A distorted trigonal-bipyramidal antimony(III) complex with a helical hydrogen-bond network

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