Synthesis of Bimetallic Uranium and Neptunium Complexes of a Binucleating Macrocycle and Determination of the Solid-State Structure by Magnetic Analysis

Polly L. Arnold; Natalie A. Potter (nee Jones); Nicola Magnani; Christos Apostolidis; Jean-Christophe Griveau; Eric Colineau; Alfred Morgenstern; Roberto Caciuffo; Jason B. Love

doi:10.1021/ic100374j

Synthesis of Bimetallic Uranium and Neptunium Complexes of a Binucleating Macrocycle and Determination of the Solid-State Structure by Magnetic Analysis

Polly L. Arnold, Natalie A. Potter (nee Jones), Nicola Magnani, Christos Apostolidis, Jean-Christophe Griveau, Eric Colineau, Alfred Morgenstern, Roberto Caciuffo, Jason B. Love

Research output: Contribution to journal › Article › peer-review

Abstract / Description of output

Syntheses of the bimetallic uranium(III) and neptunium(III) complexes [(Ul)₂(L)], [(Npl)₂(L)], and [{U(BH₄)}₂(L)] of the Schiff-base pyrrole macrocycles L are described. In the absence of single-crystal, structural data, fitting of the variable-temperature solid-state magnetic data allows the prediction of polymeric structures for these compounds in the solid state.

Original language	English
Pages (from-to)	5341-5343
Number of pages	3
Journal	Inorganic Chemistry
Volume	49
Issue number	12
Early online date	26 May 2010
DOIs	https://doi.org/10.1021/ic100374j
Publication status	Published - 21 Jun 2010

Keywords / Materials (for Non-textual outputs)

SINGLE-MOLECULE MAGNETS
SCHIFF-BASE
ACTINIDE
LANTHANIDE
COMMUNICATION
LIGANDS
OXO

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10.1021/ic100374j

Synthesis of Bimetallic Uranium and Neptunium Complexes of a Binucleating Macrocycle and Determination of the Solid-State Structure by Magnetic Analysis
Copyright © 2010 by the American Chemical Society. All rights reserved.
Accepted author manuscript, 530 KB

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Arnold, P. L., Potter (nee Jones), N. A., Magnani, N., Apostolidis, C., Griveau, J.-C., Colineau, E., Morgenstern, A., Caciuffo, R., & Love, J. B. (2010). Synthesis of Bimetallic Uranium and Neptunium Complexes of a Binucleating Macrocycle and Determination of the Solid-State Structure by Magnetic Analysis. Inorganic Chemistry, 49(12), 5341-5343. https://doi.org/10.1021/ic100374j

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title = "Synthesis of Bimetallic Uranium and Neptunium Complexes of a Binucleating Macrocycle and Determination of the Solid-State Structure by Magnetic Analysis",

abstract = "Syntheses of the bimetallic uranium(III) and neptunium(III) complexes [(Ul)2(L)], [(Npl)2(L)], and [{U(BH4)}2(L)] of the Schiff-base pyrrole macrocycles L are described. In the absence of single-crystal, structural data, fitting of the variable-temperature solid-state magnetic data allows the prediction of polymeric structures for these compounds in the solid state.",

keywords = "SINGLE-MOLECULE MAGNETS, SCHIFF-BASE, ACTINIDE, LANTHANIDE, COMMUNICATION, LIGANDS, OXO",

author = "Arnold, {Polly L.} and {Potter (nee Jones)}, {Natalie A.} and Nicola Magnani and Christos Apostolidis and Jean-Christophe Griveau and Eric Colineau and Alfred Morgenstern and Roberto Caciuffo and Love, {Jason B.}",

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doi = "10.1021/ic100374j",

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Arnold, PL, Potter (nee Jones), NA, Magnani, N, Apostolidis, C, Griveau, J-C, Colineau, E, Morgenstern, A, Caciuffo, R & Love, JB 2010, 'Synthesis of Bimetallic Uranium and Neptunium Complexes of a Binucleating Macrocycle and Determination of the Solid-State Structure by Magnetic Analysis', Inorganic Chemistry, vol. 49, no. 12, pp. 5341-5343. https://doi.org/10.1021/ic100374j

TY - JOUR

T1 - Synthesis of Bimetallic Uranium and Neptunium Complexes of a Binucleating Macrocycle and Determination of the Solid-State Structure by Magnetic Analysis

AU - Arnold, Polly L.

AU - Potter (nee Jones), Natalie A.

AU - Magnani, Nicola

AU - Apostolidis, Christos

AU - Griveau, Jean-Christophe

AU - Colineau, Eric

AU - Morgenstern, Alfred

AU - Caciuffo, Roberto

AU - Love, Jason B.

PY - 2010/6/21

Y1 - 2010/6/21

N2 - Syntheses of the bimetallic uranium(III) and neptunium(III) complexes [(Ul)2(L)], [(Npl)2(L)], and [{U(BH4)}2(L)] of the Schiff-base pyrrole macrocycles L are described. In the absence of single-crystal, structural data, fitting of the variable-temperature solid-state magnetic data allows the prediction of polymeric structures for these compounds in the solid state.

AB - Syntheses of the bimetallic uranium(III) and neptunium(III) complexes [(Ul)2(L)], [(Npl)2(L)], and [{U(BH4)}2(L)] of the Schiff-base pyrrole macrocycles L are described. In the absence of single-crystal, structural data, fitting of the variable-temperature solid-state magnetic data allows the prediction of polymeric structures for these compounds in the solid state.

KW - SINGLE-MOLECULE MAGNETS

KW - SCHIFF-BASE

KW - ACTINIDE

KW - LANTHANIDE

KW - COMMUNICATION

KW - LIGANDS

KW - OXO

UR - http://www.scopus.com/inward/record.url?scp=77953595284&partnerID=8YFLogxK

U2 - 10.1021/ic100374j

DO - 10.1021/ic100374j

M3 - Article

SN - 0020-1669

VL - 49

SP - 5341

EP - 5343

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 12

ER -

Synthesis of Bimetallic Uranium and Neptunium Complexes of a Binucleating Macrocycle and Determination of the Solid-State Structure by Magnetic Analysis

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