Synthesis of cardo-polymers using Tröger's base formation

Mariolino Carta; Matthew Croad; Johannes C. Jansen; Paola Bernardo; Gabriele Clarizia; Neil B. McKeown

doi:10.1039/c4py00607k

Synthesis of cardo-polymers using Tröger's base formation

Mariolino Carta, Matthew Croad, Johannes C. Jansen, Paola Bernardo, Gabriele Clarizia, Neil B. McKeown^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract / Description of output

A series of novel cardo-polymers was prepared using a polymerisation reaction based on Tröger's base formation. The precursor dianiline monomers are readily available from the reactions between appropriate anilines and cyclic ketones. One adamantyl-based cardo-polymer displays intrinsic microporosity with an apparent BET surface area of 615 m² g^-1. This polymer demonstrates a combination of good solubility and high molecular mass facilitating the solvent casting of robust films suitable for gas permeability measurements. The intrinsic microporosity of the polymer provides high gas permeabilities and moderate selectivities with particular promise for gas separations involving hydrogen.

Original language	English
Pages (from-to)	5255-5261
Number of pages	7
Journal	Polymer Chemistry
Volume	5
Issue number	18
Early online date	20 Jun 2014
DOIs	https://doi.org/10.1039/c4py00607k
Publication status	Published - 21 Sept 2014

Keywords / Materials (for Non-textual outputs)

INTRINSIC MICROPOROSITY PIMS
GAS SEPARATION MEMBRANES
TRANSPORT-PROPERTIES
HETEROGENEOUS CATALYSIS
SOLUBLE POLYIMIDES
PERFORMANCE

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Synthesis of cardo-polymers using Tröger's base formation
Copyright © 2014 Royal Society of Chemistry. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the RSC.
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title = "Synthesis of cardo-polymers using Tr{\"o}ger's base formation",

abstract = "A series of novel cardo-polymers was prepared using a polymerisation reaction based on Tr{\"o}ger's base formation. The precursor dianiline monomers are readily available from the reactions between appropriate anilines and cyclic ketones. One adamantyl-based cardo-polymer displays intrinsic microporosity with an apparent BET surface area of 615 m2 g-1. This polymer demonstrates a combination of good solubility and high molecular mass facilitating the solvent casting of robust films suitable for gas permeability measurements. The intrinsic microporosity of the polymer provides high gas permeabilities and moderate selectivities with particular promise for gas separations involving hydrogen.",

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author = "Mariolino Carta and Matthew Croad and Jansen, {Johannes C.} and Paola Bernardo and Gabriele Clarizia and McKeown, {Neil B.}",

year = "2014",

month = sep,

day = "21",

doi = "10.1039/c4py00607k",

language = "English",

volume = "5",

pages = "5255--5261",

journal = "Polymer Chemistry",

issn = "1759-9954",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Synthesis of cardo-polymers using Tröger's base formation

AU - Carta, Mariolino

AU - Croad, Matthew

AU - Jansen, Johannes C.

AU - Bernardo, Paola

AU - Clarizia, Gabriele

AU - McKeown, Neil B.

PY - 2014/9/21

Y1 - 2014/9/21

N2 - A series of novel cardo-polymers was prepared using a polymerisation reaction based on Tröger's base formation. The precursor dianiline monomers are readily available from the reactions between appropriate anilines and cyclic ketones. One adamantyl-based cardo-polymer displays intrinsic microporosity with an apparent BET surface area of 615 m2 g-1. This polymer demonstrates a combination of good solubility and high molecular mass facilitating the solvent casting of robust films suitable for gas permeability measurements. The intrinsic microporosity of the polymer provides high gas permeabilities and moderate selectivities with particular promise for gas separations involving hydrogen.

AB - A series of novel cardo-polymers was prepared using a polymerisation reaction based on Tröger's base formation. The precursor dianiline monomers are readily available from the reactions between appropriate anilines and cyclic ketones. One adamantyl-based cardo-polymer displays intrinsic microporosity with an apparent BET surface area of 615 m2 g-1. This polymer demonstrates a combination of good solubility and high molecular mass facilitating the solvent casting of robust films suitable for gas permeability measurements. The intrinsic microporosity of the polymer provides high gas permeabilities and moderate selectivities with particular promise for gas separations involving hydrogen.

KW - INTRINSIC MICROPOROSITY PIMS

KW - GAS SEPARATION MEMBRANES

KW - TRANSPORT-PROPERTIES

KW - HETEROGENEOUS CATALYSIS

KW - SOLUBLE POLYIMIDES

KW - PERFORMANCE

U2 - 10.1039/c4py00607k

DO - 10.1039/c4py00607k

M3 - Article

SN - 1759-9954

VL - 5

SP - 5255

EP - 5261

JO - Polymer Chemistry

JF - Polymer Chemistry

IS - 18

ER -

Synthesis of cardo-polymers using Tröger's base formation

Abstract / Description of output

Keywords / Materials (for Non-textual outputs)

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