Synthesis of novel transition metal nitrides IrN2 and OsN2

AF Young, C Sanloup, E Gregoryanz, S Scandolo, RJ Hemley, HK Mao

Research output: Contribution to journalArticlepeer-review

Abstract

Two new transition metal nitrides, IrN2 and OsN2, were synthesized at high pressures and temperatures using laser-heated diamond-anvil cell techniques. Synchrotron x-ray diffraction was used to determine the structures of novel nitrides and the equations of states of both the parent metals as well as the newly synthesized materials. The compounds have bulk moduli comparable with those of the traditional superhard materials. For IrN2, the measured bulk modulus [K-0=428(12) GPa] is second only to that of diamond (K-0=440 GPa). Ab initio calculations indicate that both compounds have a metal:nitrogen stoichiometry of 12 and that nitrogen intercalates in the lattice of the parent metal in the form of single-bonded N-N units.

Original languageEnglish
Article number155501
Number of pages4
JournalPhysical Review Letters
Volume96
Issue number15
DOIs
Publication statusPublished - 21 Apr 2006

Keywords

  • SUPERHARD MATERIALS

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