Synthesis, structure and magnetic properties of a decametallic Ni single-molecule magnet

G  Aromi; S  Parsons; W  Wernsdorfer; E K  Brechin; E J L  McInnes

doi:10.1039/b510097f

Synthesis, structure and magnetic properties of a decametallic Ni single-molecule magnet

G Aromi, S Parsons, W Wernsdorfer, E K Brechin, E J L McInnes

Research output: Contribution to journal › Article › peer-review

Abstract

Ferromagnetic exchange between the ten Ni2+ ions in the complex [Ni-10(tmp)(2)(N-3)(8)(acac)(6)(MeOH)(6)] leads to a spin ground state of S = 10; single crystal M vs. H studies reveal the temperature and sweep rate dependent hysteresis loops expected for a single-molecule magnet.

Original language	English
Pages (from-to)	5038-5040
Number of pages	3
Journal	Chemical Communications
Issue number	40
DOIs	https://doi.org/10.1039/b510097f
Publication status	Published - 2005

Keywords / Materials (for Non-textual outputs)

MIXED-VALENCE
MAGNETOSTRUCTURAL CORRELATIONS
MANGANESE CLUSTER
HIGH-NUCLEARITY
GROUND-STATE
COMPLEXES
SPIN
BEHAVIOR

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10.1039/b510097f

Cite this

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title = "Synthesis, structure and magnetic properties of a decametallic Ni single-molecule magnet",

abstract = "Ferromagnetic exchange between the ten Ni2+ ions in the complex [Ni-10(tmp)(2)(N-3)(8)(acac)(6)(MeOH)(6)] leads to a spin ground state of S = 10; single crystal M vs. H studies reveal the temperature and sweep rate dependent hysteresis loops expected for a single-molecule magnet.",

keywords = "MIXED-VALENCE, MAGNETOSTRUCTURAL CORRELATIONS, MANGANESE CLUSTER, HIGH-NUCLEARITY, GROUND-STATE, COMPLEXES, SPIN, BEHAVIOR",

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language = "English",

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journal = "Chemical Communications",

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T1 - Synthesis, structure and magnetic properties of a decametallic Ni single-molecule magnet

AU - Aromi, G

AU - Parsons, S

AU - Wernsdorfer, W

AU - Brechin, E K

AU - McInnes, E J L

PY - 2005

Y1 - 2005

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AB - Ferromagnetic exchange between the ten Ni2+ ions in the complex [Ni-10(tmp)(2)(N-3)(8)(acac)(6)(MeOH)(6)] leads to a spin ground state of S = 10; single crystal M vs. H studies reveal the temperature and sweep rate dependent hysteresis loops expected for a single-molecule magnet.

KW - MIXED-VALENCE

KW - MAGNETOSTRUCTURAL CORRELATIONS

KW - MANGANESE CLUSTER

KW - HIGH-NUCLEARITY

KW - GROUND-STATE

KW - COMPLEXES

KW - SPIN

KW - BEHAVIOR

U2 - 10.1039/b510097f

DO - 10.1039/b510097f

M3 - Article

SN - 1359-7345

SP - 5038

EP - 5040

JO - Chemical Communications

JF - Chemical Communications

IS - 40

ER -

Synthesis, structure and magnetic properties of a decametallic Ni single-molecule magnet

Abstract

Keywords / Materials (for Non-textual outputs)

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