Synthesis, structure and magnetic properties of a decametallic Ni single-molecule magnet

G Aromi, S Parsons, W Wernsdorfer, E K Brechin, E J L McInnes

Research output: Contribution to journalArticlepeer-review

Abstract / Description of output

Ferromagnetic exchange between the ten Ni2+ ions in the complex [Ni-10(tmp)(2)(N-3)(8)(acac)(6)(MeOH)(6)] leads to a spin ground state of S = 10; single crystal M vs. H studies reveal the temperature and sweep rate dependent hysteresis loops expected for a single-molecule magnet.

Original languageEnglish
Pages (from-to)5038-5040
Number of pages3
JournalChemical Communications
Issue number40
DOIs
Publication statusPublished - 2005

Keywords / Materials (for Non-textual outputs)

  • MIXED-VALENCE
  • MAGNETOSTRUCTURAL CORRELATIONS
  • MANGANESE CLUSTER
  • HIGH-NUCLEARITY
  • GROUND-STATE
  • COMPLEXES
  • SPIN
  • BEHAVIOR

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