T-shaped cationic Cu-I complexes with hemilabile PNP-type ligands

Jarl Ivar van der Vlugt; Evgeny A. Pidko; Dieter Vogt; Martin Lutz; Anthony L. Spek; Auke Meetsma

doi:10.1021/ic800298a

T-shaped cationic Cu-I complexes with hemilabile PNP-type ligands

Jarl Ivar van der Vlugt, Evgeny A. Pidko, Dieter Vogt, Martin Lutz, Anthony L. Spek, Auke Meetsma

Research output: Contribution to journal › Article › peer-review

Abstract / Description of output

The versatile coordination behavior of the PNP ligands 1A (2,6-bis[(di-tert-butylphosphino)methyl]pyridine) and 1B (2,6-bis[(diphenylphosphino)methyl]pyridine) to Cu-I is described, whereby a hemilabile interaction of the pyridine N-donor atom to the copper center resulted in a rare T-shaped complex with 1A, while with 1B also a tetracoordinated species could be isolated. Theoretical calculations support the weak interaction of the pyridine N donor in 1A with the Cu center.

Original language	English
Pages (from-to)	4442-4444
Number of pages	3
Journal	Inorganic Chemistry
Volume	47
Issue number	11
DOIs	https://doi.org/10.1021/ic800298a
Publication status	Published - 2 Jun 2008

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title = "T-shaped cationic Cu-I complexes with hemilabile PNP-type ligands",

abstract = "The versatile coordination behavior of the PNP ligands 1A (2,6-bis[(di-tert-butylphosphino)methyl]pyridine) and 1B (2,6-bis[(diphenylphosphino)methyl]pyridine) to Cu-I is described, whereby a hemilabile interaction of the pyridine N-donor atom to the copper center resulted in a rare T-shaped complex with 1A, while with 1B also a tetracoordinated species could be isolated. Theoretical calculations support the weak interaction of the pyridine N donor in 1A with the Cu center.",

author = "{van der Vlugt}, {Jarl Ivar} and Pidko, {Evgeny A.} and Dieter Vogt and Martin Lutz and Spek, {Anthony L.} and Auke Meetsma",

year = "2008",

month = jun,

day = "2",

doi = "10.1021/ic800298a",

language = "English",

volume = "47",

pages = "4442--4444",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "11",

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T1 - T-shaped cationic Cu-I complexes with hemilabile PNP-type ligands

AU - van der Vlugt, Jarl Ivar

AU - Pidko, Evgeny A.

AU - Vogt, Dieter

AU - Lutz, Martin

AU - Spek, Anthony L.

AU - Meetsma, Auke

PY - 2008/6/2

Y1 - 2008/6/2

N2 - The versatile coordination behavior of the PNP ligands 1A (2,6-bis[(di-tert-butylphosphino)methyl]pyridine) and 1B (2,6-bis[(diphenylphosphino)methyl]pyridine) to Cu-I is described, whereby a hemilabile interaction of the pyridine N-donor atom to the copper center resulted in a rare T-shaped complex with 1A, while with 1B also a tetracoordinated species could be isolated. Theoretical calculations support the weak interaction of the pyridine N donor in 1A with the Cu center.

AB - The versatile coordination behavior of the PNP ligands 1A (2,6-bis[(di-tert-butylphosphino)methyl]pyridine) and 1B (2,6-bis[(diphenylphosphino)methyl]pyridine) to Cu-I is described, whereby a hemilabile interaction of the pyridine N-donor atom to the copper center resulted in a rare T-shaped complex with 1A, while with 1B also a tetracoordinated species could be isolated. Theoretical calculations support the weak interaction of the pyridine N donor in 1A with the Cu center.

U2 - 10.1021/ic800298a

DO - 10.1021/ic800298a

M3 - Article

SN - 0020-1669

VL - 47

SP - 4442

EP - 4444

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 11

ER -

T-shaped cationic Cu-I complexes with hemilabile PNP-type ligands

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