Abstract
The syntheses, structures and magnetic properties of a host of polymetallic 3d transition-metal clusters made with the pro-ligand benzotriazole (BtaH) and its analogues are reported. These range from a family of tetradecametallic clusters with spin ground states as large as S approximate to 25, to decametallic vanadium "boxes", to iron and manganese tetra- and super-tetrahedra, to hexaicosametallic manganese single-molecule magnets. (c) Wiley-VCH Verlag GmbH & Co.
| Original language | English |
|---|---|
| Pages (from-to) | 2725-2733 |
| Number of pages | 9 |
| Journal | European journal of inorganic chemistry |
| Issue number | 14 |
| DOIs | |
| Publication status | Published - 17 Jul 2006 |
Keywords / Materials (for Non-textual outputs)
- benzotriazole
- clusters
- transition metals
- large spin ground states
- single-molecule magnets
- SINGLE-MOLECULE MAGNETS
- HIGH-SPIN MOLECULES
- GROUND-STATE
- HIGH-NUCLEARITY
- COMPLEXES
- FLUORIDE
- MAGNETIZATION
- CRYSTAL
- NANOMAGNETS
- MANGANESE
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