Abstract
The one-pot synthesis of a molecular Solomon link assembles four iron(II) cations, four bis(aldehyde) molecules, and four bis(amine) building blocks. The process generates two interwoven 68-membered-ring macrocycles, which feature four crossing points, in 75 % yield.
Original language | English |
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Pages (from-to) | 6464-6467 |
Number of pages | 4 |
Journal | Angewandte Chemie International Edition |
Volume | 52 |
Issue number | 25 |
DOIs | |
Publication status | Published - 17 Jun 2013 |
Keywords / Materials (for Non-textual outputs)
- catenanes
- chemical topology
- cyclic helicates
- molecular knot
- self-assembly
- STACKING INTERACTIONS
- TEMPLATED SYNTHESIS
- KNOTS
- EQUILIBRIUM
- CATENANES
- METALLACYCLOPHANES
- PALLADIUM(II)
- COMPLEXES
- CHEMISTRY
- COPPER(I)