Tetrameric Cyclic Double Helicates as a Scaffold for a Molecular Solomon Link

Jonathon E. Beves; Christopher J. Campbell; David A. Leigh; Robin G. Pritchard

doi:10.1002/anie.201302634

Tetrameric Cyclic Double Helicates as a Scaffold for a Molecular Solomon Link

Jonathon E. Beves, Christopher J. Campbell, David A. Leigh^*, Robin G. Pritchard

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The one-pot synthesis of a molecular Solomon link assembles four iron(II) cations, four bis(aldehyde) molecules, and four bis(amine) building blocks. The process generates two interwoven 68-membered-ring macrocycles, which feature four crossing points, in 75 % yield.

Original language	English
Pages (from-to)	6464-6467
Number of pages	4
Journal	Angewandte Chemie International Edition
Volume	52
Issue number	25
DOIs	https://doi.org/10.1002/anie.201302634
Publication status	Published - 17 Jun 2013

Keywords

catenanes
chemical topology
cyclic helicates
molecular knot
self-assembly
STACKING INTERACTIONS
TEMPLATED SYNTHESIS
KNOTS
EQUILIBRIUM
CATENANES
METALLACYCLOPHANES
PALLADIUM(II)
COMPLEXES
CHEMISTRY
COPPER(I)

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10.1002/anie.201302634

http://onlinelibrary.wiley.com/doi/10.1002/anie.201302634/full

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title = "Tetrameric Cyclic Double Helicates as a Scaffold for a Molecular Solomon Link",

abstract = "The one-pot synthesis of a molecular Solomon link assembles four iron(II) cations, four bis(aldehyde) molecules, and four bis(amine) building blocks. The process generates two interwoven 68-membered-ring macrocycles, which feature four crossing points, in 75 % yield.",

keywords = "catenanes, chemical topology, cyclic helicates, molecular knot, self-assembly, STACKING INTERACTIONS, TEMPLATED SYNTHESIS, KNOTS, EQUILIBRIUM, CATENANES, METALLACYCLOPHANES, PALLADIUM(II), COMPLEXES, CHEMISTRY, COPPER(I)",

author = "Beves, {Jonathon E.} and Campbell, {Christopher J.} and Leigh, {David A.} and Pritchard, {Robin G.}",

year = "2013",

month = jun,

day = "17",

doi = "10.1002/anie.201302634",

language = "English",

volume = "52",

pages = "6464--6467",

journal = "Angewandte Chemie International Edition",

issn = "1433-7851",

publisher = "WILEY-V C H VERLAG GMBH",

number = "25",

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TY - JOUR

T1 - Tetrameric Cyclic Double Helicates as a Scaffold for a Molecular Solomon Link

AU - Beves, Jonathon E.

AU - Campbell, Christopher J.

AU - Leigh, David A.

AU - Pritchard, Robin G.

PY - 2013/6/17

Y1 - 2013/6/17

N2 - The one-pot synthesis of a molecular Solomon link assembles four iron(II) cations, four bis(aldehyde) molecules, and four bis(amine) building blocks. The process generates two interwoven 68-membered-ring macrocycles, which feature four crossing points, in 75 % yield.

AB - The one-pot synthesis of a molecular Solomon link assembles four iron(II) cations, four bis(aldehyde) molecules, and four bis(amine) building blocks. The process generates two interwoven 68-membered-ring macrocycles, which feature four crossing points, in 75 % yield.

KW - catenanes

KW - chemical topology

KW - cyclic helicates

KW - molecular knot

KW - self-assembly

KW - STACKING INTERACTIONS

KW - TEMPLATED SYNTHESIS

KW - KNOTS

KW - EQUILIBRIUM

KW - CATENANES

KW - METALLACYCLOPHANES

KW - PALLADIUM(II)

KW - COMPLEXES

KW - CHEMISTRY

KW - COPPER(I)

U2 - 10.1002/anie.201302634

DO - 10.1002/anie.201302634

M3 - Article

VL - 52

SP - 6464

EP - 6467

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

SN - 1433-7851

IS - 25

ER -

Tetrameric Cyclic Double Helicates as a Scaffold for a Molecular Solomon Link

Abstract

Keywords

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