Tetravalent cerium carbene complexes

Ian J. Casely; Stephen T. Liddle; Alexander J. Blake; Claire Wilson; Polly L. Arnold

doi:10.1039/b713041d

Tetravalent cerium carbene complexes

Ian J. Casely, Stephen T. Liddle, Alexander J. Blake, Claire Wilson, Polly L. Arnold

Research output: Contribution to journal › Article › peer-review

Abstract

The tetravalent organometallic cerium complex [CeL4] is readily accessible from the oxidation of the trivalent [CeL3], L = a bidentate N-heterocyclic carbene alkoxide ligand, [C{(NPri)-CHCHN}CH2CMe2O]. The [CeL4] complex should behave like the [UL4] analogue, but the two complexes show significantly different structures, highlighting the differences between 4f and 5f metals.

Original language	English
Pages (from-to)	5037-5039
Number of pages	3
Journal	Chemical Communications
Issue number	47
DOIs	https://doi.org/10.1039/b713041d
Publication status	Published - 2007

Keywords / Materials (for Non-textual outputs)

N-HETEROCYCLIC CARBENE
ALKOXIDE COMPLEXES
OXIDATION
REACTIVITY
ELEMENT
STATE

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10.1039/b713041d

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title = "Tetravalent cerium carbene complexes",

abstract = "The tetravalent organometallic cerium complex [CeL4] is readily accessible from the oxidation of the trivalent [CeL3], L = a bidentate N-heterocyclic carbene alkoxide ligand, [C{(NPri)-CHCHN}CH2CMe2O]. The [CeL4] complex should behave like the [UL4] analogue, but the two complexes show significantly different structures, highlighting the differences between 4f and 5f metals.",

keywords = "N-HETEROCYCLIC CARBENE, ALKOXIDE COMPLEXES, OXIDATION, REACTIVITY, ELEMENT, STATE",

author = "Casely, {Ian J.} and Liddle, {Stephen T.} and Blake, {Alexander J.} and Claire Wilson and Arnold, {Polly L.}",

year = "2007",

doi = "10.1039/b713041d",

language = "English",

pages = "5037--5039",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "47",

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TY - JOUR

T1 - Tetravalent cerium carbene complexes

AU - Casely, Ian J.

AU - Liddle, Stephen T.

AU - Blake, Alexander J.

AU - Wilson, Claire

AU - Arnold, Polly L.

PY - 2007

Y1 - 2007

N2 - The tetravalent organometallic cerium complex [CeL4] is readily accessible from the oxidation of the trivalent [CeL3], L = a bidentate N-heterocyclic carbene alkoxide ligand, [C{(NPri)-CHCHN}CH2CMe2O]. The [CeL4] complex should behave like the [UL4] analogue, but the two complexes show significantly different structures, highlighting the differences between 4f and 5f metals.

AB - The tetravalent organometallic cerium complex [CeL4] is readily accessible from the oxidation of the trivalent [CeL3], L = a bidentate N-heterocyclic carbene alkoxide ligand, [C{(NPri)-CHCHN}CH2CMe2O]. The [CeL4] complex should behave like the [UL4] analogue, but the two complexes show significantly different structures, highlighting the differences between 4f and 5f metals.

KW - N-HETEROCYCLIC CARBENE

KW - ALKOXIDE COMPLEXES

KW - OXIDATION

KW - REACTIVITY

KW - ELEMENT

KW - STATE

U2 - 10.1039/b713041d

DO - 10.1039/b713041d

M3 - Article

SN - 1359-7345

SP - 5037

EP - 5039

JO - Chemical Communications

JF - Chemical Communications

IS - 47

ER -

Tetravalent cerium carbene complexes

Abstract

Keywords / Materials (for Non-textual outputs)

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