The anion of a phenyltris(alkylamino)phosphonium (PhTAP) salt as a chelating ligand: Synthesis and X-ray crystal structure of a 16-electron ruthenium(II) organometallic complex

P J Bailey, K J Grant, S Parsons

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Abstract

The phosphonium salt [PhP((NHPr)-Pr-i)(3)]Br has been synthesized, and the ligand properties of its deprotonated forms have been investigated. Treatment of its dilithiate Li-2[PhP((NPr)-Pr-i)(3)] with the dimer [(eta-p-cymene)RuCl2](2) provides the unsaturated 16-electron cation [(eta-p-cymene)Ru{eta(2)-((PrN)-Pr-i)(2)PPh((NHPr)-Pr-i)}](+) which adds cyanide and carbon monoxide (reversibly) and has been structurally characterized as its tetraphenylborate salt.

Original languageEnglish
Pages (from-to)551-555
Number of pages5
JournalOrganometallics
Volume17
Issue number4
Publication statusPublished - 16 Feb 1998

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