The Apparent Surface Free Energy of Rare Earth Oxides is Governed by Hydrocarbon Adsorption

Junho Oh*, Dani Orejon Mantecon, Wooyoung Park, Hyeongyun Cha, Soumyadip Sett, Yukihiro Yokoyama, Vincent Thoreton, Yasuyuki Takata, Nenad Miljkovic

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

The surface free energy of rare earth oxides (REOs) has been debated during the last decade, with some reporting REOs to be intrinsically hydrophilic, while others reporting hydrophobic. Here, we investigate the wettability and surface chemistry of pristine and smooth REO surfaces, conclusively showing that hydrophobicity stems from wettability transition due to VOC adsorption. We show that for indoor ambient atmospheres and well-controlled saturated hydrocarbon atmospheres, the apparent advancing and receding contact angles of water increase with exposure time. We examined the surfaces comprehensively with multiple surface analysis techniques to confirm hydrocarbon adsorption and correlate it to wettability transition mechanisms. We demonstrate that both physisorption and chemisorption occur on the surface, with chemisorbed hydrocarbons promoting further physisorption due to their high affinity with similar hydrocarbon molecules. This study offers a better understanding of the intrinsic wettability of REOs and provides design guidelines for REO-based durable hydrophobic coatings.
Original languageEnglish
Article number103691
JournaliScience
Volume25
Issue number1
Early online date25 Dec 2021
DOIs
Publication statusPublished - 21 Jan 2022

Keywords

  • Inorganic materials
  • Materials Science
  • Materials chemistry
  • Materials characterization
  • Materials application

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