The first alkaline earth metal complex containing a μ-η11 allyl ligand: Structure of [{HC[C(tBu)NC6H3 (CHMe2)2]2Mg (C3H5)}6]

P. J. Bailey*, S. T. Liddle, C. A. Morrison, S. Parsons

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

The cyclic hexanuclear species {{HC[C(tBu)NAr′]2Mg (C3H5)}6} (see structure) in which the allyl group exhibits μ-n1:n1 bonding is formed on thermal treatment of {HC{C(tBu)NAr′}2Mg(C3H5)(thl)} under vacuum. Ar′=2.6-diisopropylphenyl.

Original languageEnglish
Pages (from-to)4463-4466
Number of pages4
JournalAngewandte Chemie - International Edition
Volume40
Issue number23
DOIs
Publication statusPublished - 3 Dec 2001

Keywords

  • Alkaline earth metals
  • Allyl ligands
  • Magnesium
  • N ligands
  • Structure elucidation

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