The first stable scandocene: synthesis and characterisation of bis(eta-2,4,5-tri-tert-butyl-1,3-diphosphacyclopentadienyl)scandium(II)

P L  Arnold; F G N  Cloke; J F  Nixon; Polly Arnold

The first stable scandocene: synthesis and characterisation of bis(eta-2,4,5-tri-tert-butyl-1,3-diphosphacyclopentadienyl)scandium(II)

P L Arnold, F G N Cloke, J F Nixon, Polly Arnold

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The first isolable example of a molecular scandium(II) complex, the dark purple scandocene [Sc(eta(5)-P2C3Bu3t)] 1, has been isolated from the cocondensation of scandium vapour with tert-butylphosphaalkyne, (BuCP)-C-t at 77 K.

Original language	English
Pages (from-to)	797-798
Number of pages	2
Journal	Chemical Communications
Issue number	7
Publication status	Published - 7 Apr 1998

Keywords / Materials (for Non-textual outputs)

RAY CRYSTAL-STRUCTURE
MOLECULAR-STRUCTURE
COMPLEX
METAL

Cite this

@article{11bd385b927e4efea8514b10da7ace47,

title = "The first stable scandocene: synthesis and characterisation of bis(eta-2,4,5-tri-tert-butyl-1,3-diphosphacyclopentadienyl)scandium(II)",

abstract = "The first isolable example of a molecular scandium(II) complex, the dark purple scandocene [Sc(eta(5)-P2C3Bu3t)] 1, has been isolated from the cocondensation of scandium vapour with tert-butylphosphaalkyne, (BuCP)-C-t at 77 K.",

keywords = "RAY CRYSTAL-STRUCTURE, MOLECULAR-STRUCTURE, COMPLEX, METAL",

author = "Arnold, {P L} and Cloke, {F G N} and Nixon, {J F} and Polly Arnold",

year = "1998",

month = apr,

day = "7",

language = "English",

pages = "797--798",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "7",

}

TY - JOUR

T1 - The first stable scandocene: synthesis and characterisation of bis(eta-2,4,5-tri-tert-butyl-1,3-diphosphacyclopentadienyl)scandium(II)

AU - Arnold, P L

AU - Cloke, F G N

AU - Nixon, J F

AU - Arnold, Polly

PY - 1998/4/7

Y1 - 1998/4/7

N2 - The first isolable example of a molecular scandium(II) complex, the dark purple scandocene [Sc(eta(5)-P2C3Bu3t)] 1, has been isolated from the cocondensation of scandium vapour with tert-butylphosphaalkyne, (BuCP)-C-t at 77 K.

AB - The first isolable example of a molecular scandium(II) complex, the dark purple scandocene [Sc(eta(5)-P2C3Bu3t)] 1, has been isolated from the cocondensation of scandium vapour with tert-butylphosphaalkyne, (BuCP)-C-t at 77 K.

KW - RAY CRYSTAL-STRUCTURE

KW - MOLECULAR-STRUCTURE

KW - COMPLEX

KW - METAL

M3 - Article

SN - 1359-7345

SP - 797

EP - 798

JO - Chemical Communications

JF - Chemical Communications

IS - 7

ER -

The first stable scandocene: synthesis and characterisation of bis(eta-2,4,5-tri-tert-butyl-1,3-diphosphacyclopentadienyl)scandium(II)

Abstract

Keywords / Materials (for Non-textual outputs)

Fingerprint

Cite this