The first structurally authenticated zerovalent heteroarene complex of a lanthanide; Synthesis and x-ray structure of bis(2,4,6-tri-tert-butylphosphorin)holmium(o)

P L  Arnold; F G N  Cloke; P B  Hitchcock; Polly Arnold

The first structurally authenticated zerovalent heteroarene complex of a lanthanide; Synthesis and x-ray structure of bis(2,4,6-tri-tert-butylphosphorin)holmium(o)

P L Arnold, F G N Cloke, P B Hitchcock, Polly Arnold

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Holmium vapour reacts with 2,4,6-tri-tert-butylphosphorin to afford the zerovalent [Ho(eta-PC(5)H(2)Bu(3)(t)-2,4,6)(2)], the first structurally characterised complex of this class.

Original language	English
Pages (from-to)	481-482
Number of pages	2
Journal	Chemical Communications
Issue number	5
Publication status	Published - 7 Mar 1997

Keywords / Materials (for Non-textual outputs)

METAL-COMPLEXES

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title = "The first structurally authenticated zerovalent heteroarene complex of a lanthanide; Synthesis and x-ray structure of bis(2,4,6-tri-tert-butylphosphorin)holmium(o)",

abstract = "Holmium vapour reacts with 2,4,6-tri-tert-butylphosphorin to afford the zerovalent [Ho(eta-PC(5)H(2)Bu(3)(t)-2,4,6)(2)], the first structurally characterised complex of this class.",

keywords = "METAL-COMPLEXES",

author = "Arnold, {P L} and Cloke, {F G N} and Hitchcock, {P B} and Polly Arnold",

year = "1997",

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pages = "481--482",

journal = "Chemical Communications",

issn = "1359-7345",

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T1 - The first structurally authenticated zerovalent heteroarene complex of a lanthanide; Synthesis and x-ray structure of bis(2,4,6-tri-tert-butylphosphorin)holmium(o)

AU - Arnold, P L

AU - Cloke, F G N

AU - Hitchcock, P B

AU - Arnold, Polly

PY - 1997/3/7

Y1 - 1997/3/7

N2 - Holmium vapour reacts with 2,4,6-tri-tert-butylphosphorin to afford the zerovalent [Ho(eta-PC(5)H(2)Bu(3)(t)-2,4,6)(2)], the first structurally characterised complex of this class.

AB - Holmium vapour reacts with 2,4,6-tri-tert-butylphosphorin to afford the zerovalent [Ho(eta-PC(5)H(2)Bu(3)(t)-2,4,6)(2)], the first structurally characterised complex of this class.

KW - METAL-COMPLEXES

M3 - Article

SN - 1359-7345

SP - 481

EP - 482

JO - Chemical Communications

JF - Chemical Communications

IS - 5

ER -

The first structurally authenticated zerovalent heteroarene complex of a lanthanide; Synthesis and x-ray structure of bis(2,4,6-tri-tert-butylphosphorin)holmium(o)

Abstract

Keywords / Materials (for Non-textual outputs)

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