The ns and nd Rydberg states of O-2 described by Hund's case (e)

H Lefebvre-Brion; T Ridley

doi:10.1063/1.2047571

The ns and nd Rydberg states of O-2 described by Hund's case (e)

H Lefebvre-Brion^*, T Ridley

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Using Hund's case (e) representation, we have obtained a simulation of the 5s Rydberg states of O-2 for J=2 by fitting the experimental data obtained recently by Sheard [J. Chem. Phys. 118, 8781 (2003)]. Our analysis permits us to include evidence of not only the mixing of Hund's case (a) states by spin-orbit interaction, but also by L and S uncouplings. This mixing is even more important for the nd Rydberg states. For the 3d Rydberg state, J=2, we have been able to suggest for the first time an assignment for both the 3d sigma (1)Pi(g) and the 3d delta (1)Pi(g) states. (c) 2005 American Institute of Physics.

Original language	English
Article number	144306
Number of pages	3
Journal	The Journal of Chemical Physics
Volume	123
Issue number	14
DOIs	https://doi.org/10.1063/1.2047571
Publication status	Published - 8 Oct 2005

Keywords

2-PHOTON SPECTROSCOPY
SIGMA

Access to Document

10.1063/1.2047571

PDF available here
Copyright © 2005 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics.
Final published version, 384 KB

http://jcp.aip.org/resource/1/jcpsa6/v123/i14/p144306_s1

Cite this

@article{7e7e2874ad8e496b9729d112c6bb9730,

title = "The ns and nd Rydberg states of O-2 described by Hund's case (e)",

abstract = "Using Hund's case (e) representation, we have obtained a simulation of the 5s Rydberg states of O-2 for J=2 by fitting the experimental data obtained recently by Sheard [J. Chem. Phys. 118, 8781 (2003)]. Our analysis permits us to include evidence of not only the mixing of Hund's case (a) states by spin-orbit interaction, but also by L and S uncouplings. This mixing is even more important for the nd Rydberg states. For the 3d Rydberg state, J=2, we have been able to suggest for the first time an assignment for both the 3d sigma (1)Pi(g) and the 3d delta (1)Pi(g) states. (c) 2005 American Institute of Physics.",

keywords = "2-PHOTON SPECTROSCOPY, SIGMA",

author = "H Lefebvre-Brion and T Ridley",

year = "2005",

month = oct,

day = "8",

doi = "10.1063/1.2047571",

language = "English",

volume = "123",

journal = "The Journal of Chemical Physics",

issn = "0021-9606",

publisher = "AMER INST PHYSICS",

number = "14",

}

TY - JOUR

T1 - The ns and nd Rydberg states of O-2 described by Hund's case (e)

AU - Lefebvre-Brion, H

AU - Ridley, T

PY - 2005/10/8

Y1 - 2005/10/8

N2 - Using Hund's case (e) representation, we have obtained a simulation of the 5s Rydberg states of O-2 for J=2 by fitting the experimental data obtained recently by Sheard [J. Chem. Phys. 118, 8781 (2003)]. Our analysis permits us to include evidence of not only the mixing of Hund's case (a) states by spin-orbit interaction, but also by L and S uncouplings. This mixing is even more important for the nd Rydberg states. For the 3d Rydberg state, J=2, we have been able to suggest for the first time an assignment for both the 3d sigma (1)Pi(g) and the 3d delta (1)Pi(g) states. (c) 2005 American Institute of Physics.

AB - Using Hund's case (e) representation, we have obtained a simulation of the 5s Rydberg states of O-2 for J=2 by fitting the experimental data obtained recently by Sheard [J. Chem. Phys. 118, 8781 (2003)]. Our analysis permits us to include evidence of not only the mixing of Hund's case (a) states by spin-orbit interaction, but also by L and S uncouplings. This mixing is even more important for the nd Rydberg states. For the 3d Rydberg state, J=2, we have been able to suggest for the first time an assignment for both the 3d sigma (1)Pi(g) and the 3d delta (1)Pi(g) states. (c) 2005 American Institute of Physics.

KW - 2-PHOTON SPECTROSCOPY

KW - SIGMA

U2 - 10.1063/1.2047571

DO - 10.1063/1.2047571

M3 - Article

VL - 123

JO - The Journal of Chemical Physics

JF - The Journal of Chemical Physics

SN - 0021-9606

IS - 14

M1 - 144306

ER -

The ns and nd Rydberg states of O-2 described by Hund's case (e)

Abstract

Keywords

Access to Document

Fingerprint

Cite this