The reaction of an iridium PNP complex with parahydrogen facilitates polarisation transfer without chemical change

Arthur J. Holmes, Peter J. Rayner, Michael J. Cowley, Gary G. R. Green, Adrian C. Whitwood, Simon B. Duckett*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

The short lived pincer complex [(C5H3N(CH2P(Bu-t)(2))(2))Ir(H)(2)(py)]BF4 is shown to be active for signal amplification by reversible exchange. This catalyst formulation enables the efficient transfer of polarization from parahydrogen to be placed into just a single molecule of the hyperpolarisation target, pyridine. When the catalysts H-1 nuclei are replaced by H-2, increased levels of substrate hyperpolarization result and when the reverse situation is examined the catalyst itself is clearly visible through hyperpolarised signals. The ligand exchange pathways of [(C5H3N(CH2P(Bu-t)(2))(2))Ir(H)(2)(py)]BF4 that are associated with this process are shown to involve the formation of 16-electron [(C5H3N(CH2P(Bu-t)(2))(2))Ir(H)(2)(py)]BF4 and the 18-electron H-2 addition product [(C5H3N(CH2P(Bu-t)(2))(2))Ir(H)(2)(py)]BF4.

Original languageEnglish
Pages (from-to)1077-1083
Number of pages7
JournalDalton Transactions
Volume44
Issue number3
DOIs
Publication statusPublished - 2015

Keywords

  • HYDROGEN INDUCED POLARIZATION
  • PINCER COMPLEXES
  • NUCLEAR-POLARIZATION
  • NMR-SPECTROSCOPY
  • BOND ACTIVATION
  • SPIN
  • RHODIUM
  • FIELD
  • DIHYDROGEN
  • MECHANISM

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