The role of structural transformations in magnetic behaviour of fluorosilicates of 3d transition metals

S K  Asadov; K V  Kamenev; V I  Kamenev; B M  Todris; E A  Zavadskii

The role of structural transformations in magnetic behaviour of fluorosilicates of 3d transition metals

S K Asadov, K V Kamenev, V I Kamenev, B M Todris, E A Zavadskii

School of Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

The stability of the structural phases in the fluorosilicate hexahydrates of some 3d transition metals MSiF6.6H(2)O where M = Mn, Fe, Co and Ni is studied in a wide range of temperatures and pressures. The results are generalized in the form of a P-T phase diagram of crystal states. The triple points, new high-pressure phases and wide ranges of metastable states between them have been discovered. The correspondence between structural and magnetic P-T phase diagrams of the series is established.

Original language	English
Pages (from-to)	7161-7171
Number of pages	11
Journal	Journal of Physics: Condensed Matter
Volume	9
Issue number	34
Publication status	Published - 25 Aug 1997

Keywords

ORIENTATIONAL PERIODIC ANTIPHASE
PHASE-TRANSFORMATION
FLUOSILICATE
PRESSURE

Cite this

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title = "The role of structural transformations in magnetic behaviour of fluorosilicates of 3d transition metals",

abstract = "The stability of the structural phases in the fluorosilicate hexahydrates of some 3d transition metals MSiF6.6H(2)O where M = Mn, Fe, Co and Ni is studied in a wide range of temperatures and pressures. The results are generalized in the form of a P-T phase diagram of crystal states. The triple points, new high-pressure phases and wide ranges of metastable states between them have been discovered. The correspondence between structural and magnetic P-T phase diagrams of the series is established.",

keywords = "ORIENTATIONAL PERIODIC ANTIPHASE, PHASE-TRANSFORMATION, FLUOSILICATE, PRESSURE",

author = "Asadov, {S K} and Kamenev, {K V} and Kamenev, {V I} and Todris, {B M} and Zavadskii, {E A}",

year = "1997",

month = aug,

day = "25",

language = "English",

volume = "9",

pages = "7161--7171",

journal = "Journal of Physics: Condensed Matter",

issn = "0953-8984",

publisher = "IOP Publishing Ltd.",

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TY - JOUR

T1 - The role of structural transformations in magnetic behaviour of fluorosilicates of 3d transition metals

AU - Asadov, S K

AU - Kamenev, K V

AU - Kamenev, V I

AU - Todris, B M

AU - Zavadskii, E A

PY - 1997/8/25

Y1 - 1997/8/25

N2 - The stability of the structural phases in the fluorosilicate hexahydrates of some 3d transition metals MSiF6.6H(2)O where M = Mn, Fe, Co and Ni is studied in a wide range of temperatures and pressures. The results are generalized in the form of a P-T phase diagram of crystal states. The triple points, new high-pressure phases and wide ranges of metastable states between them have been discovered. The correspondence between structural and magnetic P-T phase diagrams of the series is established.

AB - The stability of the structural phases in the fluorosilicate hexahydrates of some 3d transition metals MSiF6.6H(2)O where M = Mn, Fe, Co and Ni is studied in a wide range of temperatures and pressures. The results are generalized in the form of a P-T phase diagram of crystal states. The triple points, new high-pressure phases and wide ranges of metastable states between them have been discovered. The correspondence between structural and magnetic P-T phase diagrams of the series is established.

KW - ORIENTATIONAL PERIODIC ANTIPHASE

KW - PHASE-TRANSFORMATION

KW - FLUOSILICATE

KW - PRESSURE

M3 - Article

VL - 9

SP - 7161

EP - 7171

JO - Journal of Physics: Condensed Matter

JF - Journal of Physics: Condensed Matter

SN - 0953-8984

IS - 34

ER -

The role of structural transformations in magnetic behaviour of fluorosilicates of 3d transition metals

Abstract

Keywords

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