Toward structural femtosecond chemical dynamics: Imaging chemistry in space and time

Michael Minitti, James Budarz, Adam Kirrander, Joe Robinson, Daniel Ratner, Thomas Northey, Jerome Hastings, Peter Weber

Research output: Contribution to journalArticlepeer-review

Abstract

We aim to observe a chemical reaction in real time using gas-phase X-ray diffraction. In our initial experiment at the Linac Coherent Light Source (LCLS), we investigated the model system 1,3-cyclohexadiene (CHD) at very low vapor pressures. This reaction serves as a benchmark for numerous transformations in organic synthesis and natural product biology. Excitation of CHD by an ultraviolet optical pulse initiates an electrocyclic reaction that transforms the closed ring system into the open-chain structure of 1,3,5-hexatriene. We describe technical points of the experimental method and present first results. We also outline an approach to analyze the data involving nonlinear least-square optimization routines that match the experimental observations with predicted diffraction patterns calculated from trajectories for nonadiabatic vibronic wave packets.
Original languageEnglish
Pages (from-to)81-91
JournalFaraday Discussions
Volume171
Early online date7 Aug 2014
DOIs
Publication statusPublished - 1 Dec 2014

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