Abstract
The synthesis, metalation, and redox properties of an acyclic bis(iminothienyl)methene L− are presented. This π-conjugated anion displays pronounced redox activity, undergoing facile one-electron oxidation to the acyclic, metal-free, neutral radical L* on reaction with FeBr2. In contrast, reaction of L− with CuI forms the unique, neutral Cu2I2(L*) complex of a ligand-centered radical, whereas reaction with the stronger oxidant AgBF4 forms the metal-free radical dication L*2+.
Original language | English |
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Journal | Angewandte Chemie International Edition |
Early online date | 4 May 2017 |
DOIs | |
Publication status | E-pub ahead of print - 4 May 2017 |
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Dive into the research topics of 'Triggering Redox Activity in a Thiophene Compound: Radical Stabilization and Coordination Chemistry'. Together they form a unique fingerprint.Profiles
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Jason Love
- School of Chemistry - Personal Chair of Molecular Inorganic Chemistry
- EaStCHEM
Person: Academic: Research Active