Turning up the spin, turning on single-molecule magnetism: from S=1 to S=7 in a [Mn-8] cluster via ligand induced structural distortion

Constantinos J. Milios, Ross Inglis, Alina Vinslava, Alessandro Prescimone, Simon Parsons, Spyros P. Perlepes, George Christou, Euan K. Brechin

Research output: Contribution to journalArticlepeer-review

Abstract

The spin ground state of a [(Mn6Mn2II)-Mn-III] cluster has been deliberately switched from S = 1 to S = 7 upon designed ligand substitution.

Original languageEnglish
Pages (from-to)2738-2740
Number of pages3
JournalChemical Communications
Issue number26
DOIs
Publication statusPublished - 2007

Keywords

  • OCTANUCLEAR
  • CARBOXYLATE

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