Using pyridine amidoximes in 3d-metal cluster chemistry: a novel ferromagnetic Ni-12 complex from the use of pyridine-2-amidoxime

Constantina Papatriantafyllopoulou; Leigh F. Jones; Tuyen D. Nguyen; Nuria Matamoros-Salvador; Luis Cunha-Silva; Filipe A. Almeida Paz; Joao Rocha; Marco Evangelisti; Euan K. Brechin; Spyros P. Perlepes

doi:10.1039/b802927j

Using pyridine amidoximes in 3d-metal cluster chemistry: a novel ferromagnetic Ni-12 complex from the use of pyridine-2-amidoxime

Constantina Papatriantafyllopoulou, Leigh F. Jones, Tuyen D. Nguyen, Nuria Matamoros-Salvador, Luis Cunha-Silva, Filipe A. Almeida Paz, Joao Rocha, Marco Evangelisti, Euan K. Brechin, Spyros P. Perlepes

Research output: Contribution to journal › Article › peer-review

Abstract

The use of pyridine-2-amidoxime in reaction with NiCl2 center dot 6H(2)O in the presence of NaOMe has led to a cationic Ni-12(II) cluster with novel structural features; each cluster molecule is a ferromagnet with a spin ground state of S = 6 arising from ferromagnetic exchange between the six octahedral Ni-II ions, but with intercationic interactions also affecting the magnetic properties.

Original language	English
Pages (from-to)	3153-3155
Number of pages	3
Journal	Dalton Transactions
Issue number	24
DOIs	https://doi.org/10.1039/b802927j
Publication status	Published - 2008

Keywords / Materials (for Non-textual outputs)

SINGLE-MOLECULE MAGNETS
FAMILY
LIGANDS
COBALT

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10.1039/b802927j

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Papatriantafyllopoulou, C., Jones, L. F., Nguyen, T. D., Matamoros-Salvador, N., Cunha-Silva, L., Paz, F. A. A., Rocha, J., Evangelisti, M., Brechin, E. K., & Perlepes, S. P. (2008). Using pyridine amidoximes in 3d-metal cluster chemistry: a novel ferromagnetic Ni-12 complex from the use of pyridine-2-amidoxime. Dalton Transactions, (24), 3153-3155. https://doi.org/10.1039/b802927j

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abstract = "The use of pyridine-2-amidoxime in reaction with NiCl2 center dot 6H(2)O in the presence of NaOMe has led to a cationic Ni-12(II) cluster with novel structural features; each cluster molecule is a ferromagnet with a spin ground state of S = 6 arising from ferromagnetic exchange between the six octahedral Ni-II ions, but with intercationic interactions also affecting the magnetic properties.",

keywords = "SINGLE-MOLECULE MAGNETS, FAMILY, LIGANDS, COBALT",

author = "Constantina Papatriantafyllopoulou and Jones, {Leigh F.} and Nguyen, {Tuyen D.} and Nuria Matamoros-Salvador and Luis Cunha-Silva and Paz, {Filipe A. Almeida} and Joao Rocha and Marco Evangelisti and Brechin, {Euan K.} and Perlepes, {Spyros P.}",

year = "2008",

doi = "10.1039/b802927j",

language = "English",

pages = "3153--3155",

journal = "Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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T1 - Using pyridine amidoximes in 3d-metal cluster chemistry: a novel ferromagnetic Ni-12 complex from the use of pyridine-2-amidoxime

AU - Papatriantafyllopoulou, Constantina

AU - Jones, Leigh F.

AU - Nguyen, Tuyen D.

AU - Matamoros-Salvador, Nuria

AU - Cunha-Silva, Luis

AU - Paz, Filipe A. Almeida

AU - Rocha, Joao

AU - Evangelisti, Marco

AU - Brechin, Euan K.

AU - Perlepes, Spyros P.

PY - 2008

Y1 - 2008

N2 - The use of pyridine-2-amidoxime in reaction with NiCl2 center dot 6H(2)O in the presence of NaOMe has led to a cationic Ni-12(II) cluster with novel structural features; each cluster molecule is a ferromagnet with a spin ground state of S = 6 arising from ferromagnetic exchange between the six octahedral Ni-II ions, but with intercationic interactions also affecting the magnetic properties.

AB - The use of pyridine-2-amidoxime in reaction with NiCl2 center dot 6H(2)O in the presence of NaOMe has led to a cationic Ni-12(II) cluster with novel structural features; each cluster molecule is a ferromagnet with a spin ground state of S = 6 arising from ferromagnetic exchange between the six octahedral Ni-II ions, but with intercationic interactions also affecting the magnetic properties.

KW - SINGLE-MOLECULE MAGNETS

KW - FAMILY

KW - LIGANDS

KW - COBALT

UR - http://www.scopus.com/inward/record.url?scp=45149105832&partnerID=8YFLogxK

U2 - 10.1039/b802927j

DO - 10.1039/b802927j

M3 - Article

SN - 0300-9246

SP - 3153

EP - 3155

JO - Dalton Transactions

JF - Dalton Transactions

IS - 24

ER -

Using pyridine amidoximes in 3d-metal cluster chemistry: a novel ferromagnetic Ni-12 complex from the use of pyridine-2-amidoxime

Abstract

Keywords / Materials (for Non-textual outputs)

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