Edinburgh Research Explorer

Complex Hydrogen Substructure in Semimetallic RuH4

Research output: Contribution to journalLetterpeer-review

Related Edinburgh Organisations

Original languageEnglish
Pages (from-to)3390-3395
Number of pages6
JournalThe Journal of Physical Chemistry Letters
Volume11
Issue number9
Early online date6 Apr 2020
DOIs
Publication statusPublished - 7 May 2020

Abstract

When compressed in a matrix of solid hydrogen, many metals form compounds with increasingly high hydrogen contents. At high density, hydrogenic sublattices can emerge, which may act as low-dimensional analogues of atomic hydrogen. We show that at high pressures and temperatures, ruthenium forms polyhydride species that exhibit intriguing hydrogen substructures with counterintuitive electronic properties. Ru3H8 is synthesized from RuH in H2 at 50 GPa and at temperatures in excess of 1000 K, adopting a cubic structure with short H–H distances. When synthesis pressures are increased above 85 GPa, we observe RuH4 which crystallizes in a remarkable structure containing corner-sharing H6 octahedra. Calculations indicate this phase is semimetallic at 100 GPa.

ID: 154421795