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High-pressure synthesis of lithium hydride

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Original languageEnglish
Article number064108
Number of pages4
JournalPhysical Review B: Condensed Matter and Materials Physics
Volume86
Issue number6
DOIs
StatePublished - 16 Aug 2012

Abstract

By compressing elemental lithium and hydrogen in a diamond anvil cell, we have synthesized lithium hydride (LiH) at pressures as low as 50 MPa at room temperature. Combined Raman spectroscopy and synchrotron x-ray diffraction measurements reveal that, once synthesized, LiH remains stable at 300 K up to 160 GPa in the presence of molecular hydrogen. The mixture of lithium hydride and molecular hydrogen and application of pressure alone cannot form a higher H-2 content hydride (LiHx, x > 1) as was suggested from the theoretical ab initio calculations and therefore, cannot be considered as a route to low-pressure hydrogen rich material metallization.

    Research areas

  • EQUATION-OF-STATE, X-RAY-DIFFRACTION, HYDROGEN STORAGE, METAL-HYDRIDES, GPA

ID: 11477228