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Topological Sieving of Rings According to Their Rigidity

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https://pubs.acs.org/doi/10.1021/acsmacrolett.8b00719
Original languageEnglish
JournalACS MACRO LETTERS
Volume7
Early online date15 Nov 2018
DOIs
Publication statusE-pub ahead of print - 15 Nov 2018

Abstract

We present a novel mechanism for resolving the mechanical rigidity of nanoscopic circular polymers that flow in a complex environment. The emergence of a regime of negative differential mobility induced by topological interactions between the rings and the substrate is the key mechanism for selective sieving of circular polymers with distinct flexibilities. A simple model accurately describes the sieving process observed in molecular dynamics simulations and yields experimentally verifiable analytical predictions, which can be used as a reference guide for improving filtration procedures of circular filaments. The topological sieving mechanism we propose ought to be relevant also in probing the microscopic details of complex substrates.

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